copper(1+) tetrachloroaluminate(1-)

Base Information

• Chemical Name: copper(1+) tetrachloroaluminate(1-)
• CAS No.: 27803-79-8
• Molecular Formula: AlCl₄*Cu
• Molecular Weight: 232.34
• Mol file: 27803-79-8.mol

Synonyms:Aluminate(1-),tetrachloro-, copper(1+) (8CI); Aluminum copper chloride (Al2Cu2Cl8); Aluminumcopper chloride (AlCuCl4); Copper aluminum chloride (Cu2Al2Cl8); Copperaluminum chloride (CuAlCl4); Copper aluminum tetrachloride; Coppertetrachloroaluminate; Copper(1+) tetrachloroaluminate(1-); Copper(I)tetrachloroaluminate; Cosorb; Cuprous aluminum tetrachloride; Cuproustetrachloroaluminate

Chemical Property of copper(1+) tetrachloroaluminate(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of copper(1+) tetrachloroaluminate(1-)

There total 3 articles about copper(1+) tetrachloroaluminate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminium trichloride (7446-70-0) + copper(l) chloride → copper aluminum chloride (27803-79-8)

Guidance literature:

In neat (no solvent); N2 atmosphere; heating (vacuum, slight excess of AlCl3, 430°C, sealed silica tube, 1 h), cooling to room temp. (10°C per h); X-ray diffraction;

DOI:10.1021/ja9925204

Reference yield:

aluminum (III) chloride (7446-70-0,7784-13-6) + copper(l) chloride → Cu(1+)*AlCl4(1-)=CuAlCl4 (27803-79-8)

Guidance literature:

at 249.84 ℃;

DOI:10.1016/j.molcata.2014.11.020

Reference yield:

copper(II) tetrachloroaluminium + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → Cu(1+)*AlCl4(1-)=CuAlCl4 (27803-79-8)

Guidance literature:

byproducts: poly(1,4-phenylene); 2.5 mmol of benzene reacted with 2.5 mmol of Cu(AlCl4)2 for 2 h at 20°C; elem. anal.;

DOI:10.1246/cl.1982.871

upstream raw materials:

benzene

aluminum (III) chloride

aluminium trichloride

Refernces

• 1、 Kitajima, Nobumasa,Hakone, Yoshiaki,Ono, Yoshio. "POLYMERIZATION OF BENZENE WITH Cu(AlCl4)2". . p. 871 - 874. Retrieved 1982.