Technology Process of C12H12O2
There total 2 articles about C12H12O2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
acetophenone;
With
copper(I) triflate benzene complex; (R)-1-{(RFc)-2-[2-(diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine; tetrabutylammonium triphenyldifluorosilicate; Triphenylphosphine oxide;
In
ethyl acetate;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
trans-1-methoxy-3-triethoxylsiloxy-1,3-butadiene;
In
ethyl acetate;
at 20 ℃;
for 120h;
optical yield given as %ee;
enantioselective reaction;
Inert atmosphere;
DOI:10.1021/ol802134a
- Guidance literature:
-
acetophenone;
With
copper(I) triflate benzene complex; (R)-1-{(RFc)-2-[2-(diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine; tetrabutylammonium triphenyldifluorosilicate; Triphenylphosphine oxide;
In
tetrahydrofuran;
at 20 ℃;
for 0.166667h;
Inert atmosphere;
With
triethoxyfluorosilane;
In
tetrahydrofuran;
at 20 ℃;
for 0.0833333h;
Inert atmosphere;
Danishefsky's diene;
In
tetrahydrofuran;
at 20 ℃;
for 24h;
optical yield given as %ee;
enantioselective reaction;
Inert atmosphere;
DOI:10.1021/ol802134a
- Guidance literature:
-
C12H12O2;
With
ozone;
In
methanol; dichloromethane;
at -90 ℃;
Inert atmosphere;
With
dimethylsulfide;
In
methanol; dichloromethane;
at -90 ℃;
for 1h;
Further stages;
Inert atmosphere;
Cooling with ice;
DOI:10.1021/ol802134a
