K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA

Base Information

• Chemical Name: K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
• CAS No.: 1159806-68-4
• Molecular Formula: C₄H₉NO*C₁₅H₃₂N₅NiO₃*K
• Molecular Weight: 515.361
• Mol file: 1159806-68-4.mol

Synonyms:K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA

Chemical Property of K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA

There total 1 articles about K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

N,N-dimethyl acetamide (127-19-5,116057-81-9) + water (7732-18-5) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) + potassium hydride + bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine (613221-93-5) → K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA (1159806-68-4) + potassium acetate (127-08-2)

Guidance literature:

In N,N-dimethyl acetamide; (Ar); treatment of soln. of urea deriv. in dimethylacetamide with 3 equiv. of KH at room temp., addn. of 1 equiv. of nickel compd. at room temp., stirring for 45 min, addn. of 1 equiv. of water, stirring for 20 min; filtration, diffusion of 1:1 ether/pentane vapour, isolation of crystals, elem. anal.;

DOI:10.1039/b820209e

Reference yield: 95.0%

K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA (1159806-68-4) + tetramethyl ammonium acetate (10581-12-1) + potassium hexamethylsilazane (40949-94-8) → [Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(oxo)](2-) + [tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(OSiMe3)] (1159806-88-8) + potassium acetate (127-08-2)

Guidance literature:

In N,N-dimethyl acetamide; (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium amide deriv. at room temp., stirring for 30 min, addn.of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of 1:1 diethyl ether/pentane vapour into soln. in dimethylacetamide, IR and UV;

DOI:10.1039/b820209e

Reference yield: 78.0%

K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA (1159806-68-4) + potassium tert-butylate (865-47-4) + tetramethyl ammonium acetate (10581-12-1) → [Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(oxo)](2-) + [tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(tert-butoxide)] (1159806-80-0) + potassium acetate (127-08-2)

Guidance literature:

In N,N-dimethyl acetamide; (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium tert-butoxide at room temp., stirring for 30 min, addn. of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of diethyl ether vapour into soln. in dimethylacetamide, IR and UV;

DOI:10.1039/b820209e

upstream raw materials:

N,N-dimethyl acetamide

water

nickel diacetate

bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine

Downstream raw materials:

[tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(tert-butoxide)]

potassium acetate

[tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(OSiMe₃)]