DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Base Information

Chemical Name:DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol
CAS No.:80065-34-5
Molecular Formula:C₁₈H₂₄BrNO₇S
Molecular Weight:478.361
Hs Code.:

Synonyms:DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Suppliers and Price of DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

There total 2 articles about DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 127-65-1
chloroamine-T

: 74766-78-2,96291-86-0,115225-42-8
3,4-di-O-acetyl-1,5-anhydro-6-bromo-2,6-dideoxy-5a-carba-DL-arabino-hex-1-enitol

: 80065-34-5
DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Guidance literature:: With osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; In chloroform; water; tert-butyl alcohol; at 60 ℃; for 40h;
DOI:10.1246/bcsj.54.2739

Reference yield:

: 69982-70-3,87100-11-6,96291-85-9,115225-41-7
3,4-di-O-acetyl-2,6-dibromo-2,6-dideoxy-5a-carba-β-DL-glucopyranosyl bromide

: 80065-34-5
DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-bromomethyl-2-(toluene-p-sulfonamido)-1,3,4-cyclohexanetriol

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / zinc dust, acetic acid / 0.17 h / 70 °C

2: 31 percent / osmium tetroxide, triethylbenzylammonium chloride / CHCl₃; H₂O; 2-methyl-propan-2-ol / 40 h / 60 °C

With osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; acetic acid; zinc; In chloroform; water; tert-butyl alcohol;
DOI:10.1246/bcsj.54.2739