Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Base Information

Chemical Name:Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester
CAS No.:575456-24-5
Molecular Formula:C₆₃H₈₉O₁₁PSi₃
Molecular Weight:1137.62
Hs Code.:

Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Synonyms:Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

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Chemical Property of Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Chemical Property:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

There total 28 articles about Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 105-13-5
4-Methoxybenzyl alcohol

: 381665-45-8
(6R)-6-{(1E,3R,4R,6R,7Z,9Z,11E)-6-{[tert-butyl(dimethyl)silyl]oxy}-13-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxy-3-methyl-3-[(triethylsilyl)oxy]trideca-1,7,9,11-tetraen-1-yl}-5,6-dihydro-2H-pyran-2-one

: 575456-24-5
Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Guidance literature:: 4-Methoxybenzyl alcohol; (6R)-6-{(1E,3R,4R,6R,7Z,9Z,11E)-6-{[tert-butyl(dimethyl)silyl]oxy}-13-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxy-3-methyl-3-[(triethylsilyl)oxy]trideca-1,7,9,11-tetraen-1-yl}-5,6-dihydro-2H-pyran-2-one; With pyridine; phosphorus trichloride;

With tert.-butylhydroperoxide; In dichloromethane; Further stages.;
DOI:10.1039/b201302a

Reference yield:

: (1Z,3E)-5-tert-butyldiphenylsilyloxy-1-tributylstannylpenta-1,3-diene

: 575456-24-5
Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: 84 percent / (MeCN)2PdCl₂ / dimethylformamide / 25 h / 20 °C

2: PCl₃; pyridine / 0.25 h / 0 °C

3: pyridine / 1 h / 0 - 20 °C

4: 7.8 mg / tert-butyl hydroperoxide / CH₂Cl₂; decane; pyridine / 1.5 h / 20 °C

With pyridine; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); phosphorus trichloride; In pyridine; decane; dichloromethane; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1021/ja030133v

Reference yield:

: 381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one

: 575456-24-5
Phosphoric acid (4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl ester bis-(4-methoxy-benzyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: 84 percent / (MeCN)2PdCl₂ / dimethylformamide / 25 h / 20 °C

2: PCl₃; pyridine / 0.25 h / 0 °C

3: pyridine / 1 h / 0 - 20 °C

4: 7.8 mg / tert-butyl hydroperoxide / CH₂Cl₂; decane; pyridine / 1.5 h / 20 °C

With pyridine; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); phosphorus trichloride; In pyridine; decane; dichloromethane; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1021/ja030133v