(2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: (2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II)
• CAS No.: 184714-17-8
• Molecular Formula: C₅₁H₄₂F₃O₃P₃RuS
• Molecular Weight: 985.945

Synonyms:(2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II)

Chemical Property of (2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II)

Chemical Property:

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Technology Process of (2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II)

There total 1 articles about (2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

(2,6-bis[(diphenylphosphino)methyl]phenyl)chloro(triphenylphosphine)ruthenium(II) (184714-11-2) + silver trifluoromethanesulfonate (2923-28-6) → (2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II) (184714-17-8)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring (room temp., dark, 3 h); centrifugation, evapn., extg. (C6H6), CH2Cl2 addn., pptn. on pentane addn., washing (hexane), drying (vac.); elem. anal.;

DOI:10.1021/om9603833

Reference yield: 85.0%

(2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II) (184714-17-8) + potassium iodide (7681-11-0) → (2,6-bis[(diphenylphosphino)methyl]phenyl)iodo(triphenylphosphine)ruthenium(II) (184714-19-0)

Guidance literature:

In methanol; N2-atmosphere; stirring (room temp., 3 h); evapn. (vac.), extg. (C6H6), centrifugation, pptn. on concg. and hexane addn., filtering, washing (pentane), drying (vac.); elem. anal.;

DOI:10.1021/om9603833

Reference yield: 81.0%

(2,6-bis[(diphenylphosphino)methyl]phenyl)trifluoromethanesulfonato(triphenylphosphine)ruthenium(II) (184714-17-8) + 1,3-bis(diphenylphosphinomethyl)benzene (89756-88-7) → C6H3(CH2P(C6H5)2)2RuC6H4(CH2P(C6H5)2)2(1+)*SO3CF3(1-)*0.75CH2Cl2=[C32H27P2RuC6H4(CH2P(C6H5)2)2]SO3CF3*0.75CH2Cl2

Guidance literature:

In dichloromethane; stirring at room temp. (0.5 h); pptn. with Et2O; elem. anal.;

DOI:10.1021/ja9710060

upstream raw materials:

(2,6-bis[(diphenylphosphino)methyl]phenyl)chloro(triphenylphosphine)ruthenium(II)

silver trifluoromethanesulfonate

Downstream raw materials:

RuH(P(C₆H₅)3)(C₆H₃(CH₂P(C₆H₅)2)2)(OCH(CH₃)2)^(1-)*K⁽¹⁺⁾=(RuH(P(C₆H₅)3)(C₆H₃(CH₂P(C₆H₅)2)2)(OCH(CH₃)2))K

1,3-(Ph₂PCH₂)2C₆H₃-2-Ru(1,3-(Ph₂PCH₂)2C₆H₄)CF₃SO₃

(2,6-bis[(diphenylphosphino)methyl]phenyl)iodo(triphenylphosphine)ruthenium(II)

(2,6-bis[(diphenylphosphine)methyl]phenyl)(2,2':6',2''-terpyridine)ruthenium(II) trifluoromethanesulfonate

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