Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Base Information

Chemical Name:Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester
CAS No.:152932-80-4
Molecular Formula:C₃₆H₄₄ClNO₁₅
Molecular Weight:766.196
Hs Code.:

Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Synonyms:Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

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Chemical Property of Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

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Technology Process of Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

There total 3 articles about Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60920-82-3
benzyl 2-acetamido-3-O-allyl-6-O-benzyl-2-deoxy-α-D-glucopyranoside

: 152932-80-4
Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / AgClO₄, SnCl₂, 4A molecular sieves / CH₂Cl₂ / 3 h / 0 - 25 °C

2: 1.) H₂Ru(PPh₃)4, 2.) p-TsOH / 1.) EtOH, 80 deg C, 1 h, 2.) MeOH, CH₂Cl₂, 25 deg C, 2 h

With dihydridotetrakis(triphenylphosphine)ruthenium; 4 A molecular sieve; silver perchlorate; toluene-4-sulfonic acid; tin(ll) chloride; In dichloromethane;
DOI:10.1021/ja00072a049

Reference yield:

: Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-fluoro-tetrahydro-pyran-4-yl ester

: 152932-80-4
Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / AgClO₄, SnCl₂, 4A molecular sieves / CH₂Cl₂ / 3 h / 0 - 25 °C

2: 1.) H₂Ru(PPh₃)4, 2.) p-TsOH / 1.) EtOH, 80 deg C, 1 h, 2.) MeOH, CH₂Cl₂, 25 deg C, 2 h

With dihydridotetrakis(triphenylphosphine)ruthenium; 4 A molecular sieve; silver perchlorate; toluene-4-sulfonic acid; tin(ll) chloride; In dichloromethane;
DOI:10.1021/ja00072a049

Reference yield:

: 152932-79-1
Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-4-allyloxy-6-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

: 152932-80-4
Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

Guidance literature:: With dihydridotetrakis(triphenylphosphine)ruthenium; toluene-4-sulfonic acid; Yield given. Multistep reaction; 1.) EtOH, 80 deg C, 1 h, 2.) MeOH, CH₂Cl₂, 25 deg C, 2 h;
DOI:10.1021/ja00072a049