[Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)

Base Information

• Chemical Name: [Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)
• CAS No.: 399039-62-4
• Molecular Formula: C₂₉H₂₇O₂P₂Pd*F₆P
• Molecular Weight: 720.864
• Mol file: 399039-62-4.mol

Synonyms:[Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)

Chemical Property of [Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)

There total 1 articles about [Pd(CO)(COCH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Pd(CH3CN)(CH3)(1,2-bis(diphenylphosphino)ethane)](PF6) (399039-50-0) + carbon monoxide (201230-82-2) → [Pd(CO)(COCH3)(1,2-bis(diphenylphosphino)ethane)](PF6) (399039-62-4)

Guidance literature:

In dichloromethane-d2; (N2); using Schlenk techniques; transferring of soln. of PdC29H30F6NP3 in CD2Cl2 into NMR tube, cooling to -80°C, immersing into bath (-117°C), treatment with 15 bar of CO, precooling to -80°C, slow heating to -40°C; monitoring by NMR; Kinetics;

DOI:10.1021/om010727b

Reference yield: 99.0%

ethene (74-85-1) + [Pd(CO)(COCH3)(1,2-bis(diphenylphosphino)ethane)](PF6) (399039-62-4) → [Pd(CH2CH2CO(CH3)(1,2-bis(diphenylphosphino)ethane)](PF6) (399039-59-9)

Guidance literature:

With CD₃CN; In dichloromethane-d2; byproducts: CO; using Schlenk techniques; immersing in bath of soln. of (Pd(CO)(COMe)(dppe))PF6 in CD2Cl2 at -30°C; addn. of CD3CN, purging with Ar; treatment with C2H4 (15 bar) at -110°C;

DOI:10.1021/om010727b

upstream raw materials:

[Pd(CH₃CN)(CH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)

carbon monoxide

Downstream raw materials:

[Pd(CH₂CH₂CO(CH₃)(1,2-bis(diphenylphosphino)ethane)](PF₆)