molybdenum thiotrichloride

Base Information

Chemical Name:molybdenum thiotrichloride
CAS No.:44014-29-1
Molecular Formula:Cl₃MoS
Molecular Weight:234.365
Hs Code.:

Synonyms:molybdenum thiotrichloride

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of molybdenum thiotrichloride

Chemical Property:

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Technology Process of molybdenum thiotrichloride

There total 1 articles about molybdenum thiotrichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3385-94-2
hexamethyldisilathiane

: 10241-05-1
molybdenum(V) chloride

: 75-77-4
chloro-trimethyl-silane

: 44014-29-1
molybdenum thiotrichloride

Guidance literature:: In dichloromethane; (vac. or Ar atmosphere) dropwise addn. of soln. of (Me3Si)2S (-30°C) to suspn. of metal compound (-78°C), stirring, warming to room temp.; high yield;
DOI:10.1016/S0277-5387(00)80757-3

Reference yield: 22.0%

: 44014-29-1
molybdenum thiotrichloride

: 791-28-6
Triphenylphosphine oxide

: MoO₂Cl₂{OP(C₆H₅)3}2*MoOSCl₂{OP(C₆H₅)3}2

: MoOCl₃{OP(C₆H₅)3}2*Mo(O,Cl)2Cl₂{OP(C₆H₅)3}2

Guidance literature:: In acetonitrile; addn. of OPPh3 to soln. of MoSCl3, boiled, 4 h, evapn., extraction with MeCN, cooled to 0°C, pptn.; evapn. (vac.), extn. (hot MeCN), cooled to 0°C, pptn. of MoOCl3(OPPh3)2*Mo(O,Cl)Cl2(OPPh3)2, sepn., dried in vacuo; extn. of residue (EtOH), cooled to -5°C, pptn. of MoSOCl2(OPPh3)2*MoO2Cl2(OPPh3)2; elem. anal.;
DOI:10.1007/BF00750181

Reference yield:

: 44014-29-1
molybdenum thiotrichloride

: 2001-45-8
tetraphenyl phosphonium chloride

: (C₆H₅)4P*MoSCl₄

Guidance literature:: In dichloromethane; direct reaction of suspension of Mo-compound with the stoichiometric amount (1:1 molar ratio) of the ligand; elem.anal.;
DOI:10.1016/0022-5088(87)90206-2