1,4-Dioxaspiro[4.5]decane, 8-methyl-

Base Information

• Chemical Name: 1,4-Dioxaspiro[4.5]decane, 8-methyl-
• CAS No.: 935-51-3
• Molecular Formula: C9H16 O2
• Molecular Weight: 156.225
• Hs Code.: 2932999099
• Mol file: 935-51-3.mol

Synonyms:1,4-Dioxaspiro[4.5]decane, 8-methyl-

Chemical Property of 1,4-Dioxaspiro[4.5]decane, 8-methyl-

Chemical Property:

• Boiling Point: 80.5 °C (25mmHg)
• PSA: 18.46000
• Density: 1.01±0.1 g/cm3 (20 °C, 760 mmHg)
• LogP: 1.93960

Purity/Quality:

99% ^*data from raw suppliers

1,4-DIOXASPIRO[4.5]DECANE, 8-METHYL- 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-Dioxaspiro[4.5]decane, 8-methyl-

There total 1 articles about 1,4-Dioxaspiro[4.5]decane, 8-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexenone (930-68-7) + ethylene glycol (107-21-1) + 1-methylcyclohexan-4-one (589-92-4) → 1,3-dioxolane-2-spirocyclohexane (177-10-6) + 8-methyl-1,4-dioxaspiro[4.5]decane. (935-51-3)

Guidance literature:

With triethylsilane; palladium dichloride; tricyclohexylphosphine; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1002/chem.201100655

Reference yield: 82.0%

8-methyl-1,4-dioxaspiro[4.5]decane. (935-51-3) → 1-methylcyclohexan-4-one (589-92-4)

Guidance literature:

With pyridinium p-toluenesulfonate; silica gel; In water; for 0.05h; microwave irradiation;

DOI:10.1081/SCC-200036616

Reference yield: 13.0%

8-methyl-1,4-dioxaspiro[4.5]decane. (935-51-3) → 1,2-Bis<(trans-4-Methylcyclohexyl)oxy>ethane + 2-<(trans-4-Methylcyclohexyl)oxy>ethan-1-ol + 2-<(cis-4-Methylcyclohexyl)oxy>ethan-1-ol

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; dimethylsulfide borane complex; In dichloromethane;

DOI:10.1021/jo00076a041

upstream raw materials:

cyclohexenone

ethylene glycol

1-methylcyclohexan-4-one

Downstream raw materials:

2-[4-Methyl-1-(3-methyl-butyl)-cyclohexyloxy]-ethanol

2-(1-Cyclohexylmethyl-4-methyl-cyclohexyloxy)-ethanol

2-(1-Benzyl-4-methyl-cyclohexyloxy)-ethanol

1-methylcyclohexan-4-one