(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

Base Information

• Chemical Name: (SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)
• CAS No.: 253604-41-0
• Molecular Formula: C₅₆H₅₉BrN₄O₁₂Zn
• Molecular Weight: 1125.4

Synonyms:(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

Chemical Property of (SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

Chemical Property:

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Technology Process of (SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

There total 1 articles about (SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoate) + zinc diacetate (557-34-6) → (SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)](2-)-N(21),N(22),N(23),N(24)]zinc(II) (253604-41-0)

Guidance literature:

In methanol; chloroform; room temp., 4 h;

DOI:10.1002/(SICI)1521-3773(19991102)38:21<3215::AID-ANIE3215>3.0.CO;2-S

Reference yield: 99.0%

(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)](2-)-N(21),N(22),N(23),N(24)]zinc(II) (253604-41-0) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → (tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc (573658-46-5)

Guidance literature:

With triethylamine; bis-triphenylphosphine-palladium(II) chloride; In 1,2-dichloro-ethane; (N2); refluxed for 18 h; cooled to 20°C, Et2O and satd. aq. soln. of NaH2PO4 added, the org. layer sepd., washed (H2O and satd. aq. NaCl), evapd. (vac.), dissolved in Et2O, filtered (SiO2, Et2O), evapd. (vac.), recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1002/hlca.200490288

Reference yield: 82.0%

(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)](2-)-N(21),N(22),N(23),N(24)]zinc(II) (253604-41-0) + 2-{3,5-bis[6-(1H-imidazol-1-yl)hexyloxy]-4-methylphenyl}-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (253604-35-2) → [Zn(C81H94N8O14)]

Guidance literature:

With caesium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; 90°C, 4 h;

DOI:10.1002/(SICI)1521-3773(19991102)38:21<3215::AID-ANIE3215>3.0.CO;2-S

upstream raw materials:

zinc diacetate

Downstream raw materials:

ZnC₂₀N₄H₉(CH₃C₆H₃OC₆H₁₂C₃N₂H₃)[C₆H₃(OC₃H₆CO₂C₂H₅)2]2

(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-(3,5-bis[[6-(1H-imidazole-1-yl)hexyl]oxy]-4-methylphenyl)-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

[Zn(((CH₃)2CH)3SiC₂C₆H₄(C₅H₂N)4H(C₆H₃(O(CH₂)3CO₂C₂H₅)2)2)]

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