N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

Base Information

• Chemical Name: N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine
• CAS No.: 1438414-25-5
• Molecular Formula: C₂₀H₂₀N₂OS
• Molecular Weight: 336.458
• Mol file: 1438414-25-5.mol

Synonyms:N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

Chemical Property of N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

There total 2 articles about N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-methoxyphenyl bromide (2398-37-0) + N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine (1378302-79-4) → N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine (1438414-25-5)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; ruphos; In toluene; at 110 ℃; for 20h;

DOI:10.1002/adsc.201200754

Reference yield:

N-(4-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine (1438414-24-4) → N-(3-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine (1438414-25-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ammonium cerium (IV) nitrate; sodium carbonate / acetonitrile; water / 0.17 h / Cooling with ice

1.2: 1 h / 20 °C

2.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; ruphos; caesium carbonate / toluene / 20 h / 110 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; ammonium cerium (IV) nitrate; sodium carbonate; caesium carbonate; ruphos; In water; toluene; acetonitrile;

DOI:10.1002/adsc.201200754

upstream raw materials:

N-(4-methoxyphenyl)-N'-phenyl-S-methyl-S-phenyl sulfondiimine

3-methoxyphenyl bromide

N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine