1378302-79-4Relevant academic research and scientific papers
Synthesis of sulfondiimines by N-chlorosuccinimide-mediated oxidative imination of sulfiliminium salts
Candy, Mathieu,Guyon, Carole,Mersmann, Stefanie,Chen, Jia-Rong,Bolm, Carsten
, p. 4440 - 4443 (2012/06/18)
Access to sulfondiimines: The oxidative one-pot chlorination-imination sequence of in situ generated free sulfilimines by N-chlorosuccinimide (NCS) allows the preparation of N-monosubstituted sulfondiimines under mild reaction conditions with excellent functional-group tolerance (see scheme; Mes=2,4,6-trimethylphenylsulfonyl) Copyright
Palladium-catalyzed C-N cross-coupling of N'-monosubstituted sulfondiimines with aryl bromides
Candy, Mathieu,Bohmann, Rebekka Anna,Bolm, Carsten
supporting information, p. 2928 - 2932 (2013/01/15)
A general method for the N-arylation of sulfondiimines with aryl bromides using tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3] and 2-dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl (RuPhos) as catalyst system was developed. A new benzothiazine was obtained, and a protocol for the cleavage of para-methoxyphenyl (PMP) groups in PMP-protected sulfondiimines has been found, which provides access to synthetically useful NH-derivatives, that are difficult to prepare by other means. Copyright
