3-BENZYLANILINE

Base Information

• Chemical Name: 3-BENZYLANILINE
• CAS No.: 61424-26-8
• Molecular Formula: C13H13N
• Molecular Weight: 183.253
• Hs Code.: 29214990
• Mol file: 61424-26-8.mol

Synonyms:m-Toluidine, a-phenyl- (6CI);3-Benzylaniline;3-Benzylbenzenamine;3-Benzylphenylamine;NSC 210972;

Chemical Property of 3-BENZYLANILINE

Chemical Property:

• Appearance/Colour: solid
• Vapor Pressure: 0.000205mmHg at 25°C
• Melting Point: 48-52 °C(lit.)
• Refractive Index: 1.616
• Boiling Point: 327.2 °C at 760 mmHg
• PKA: 4.67±0.10(Predicted)
• Flash Point: 162.5 °C
• PSA: 26.02000
• Density: 1.07 g/cm³
• LogP: 3.44080
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-?Benzylaniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 16-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 3-BENZYLANILINE

There total 12 articles about 3-BENZYLANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2-chloro-5-nitro-benzophenone oxime (141883-38-7) → 3-benzylaniline (61424-26-8)

Guidance literature:

With ammonium formate; palladium on activated charcoal; In methanol; for 3h; Ambient temperature;

Reference yield: 68.0%

3-amino benzophenone (2835-78-1) → 3-benzylaniline (61424-26-8)

Guidance literature:

With aluminum (III) chloride; lithium aluminium tetrahydride; In diethyl ether; at 0 - 20 ℃; for 3h;

DOI:10.1016/j.ejmech.2017.04.010

Reference yield:

1-benzyl-3-nitrobenzene (5840-41-5) + 3-Nitrobenzyl chloride (619-23-8) → 3-benzylaniline (61424-26-8)

Guidance literature:

With ammonium hydroxide; sodium sulfide; aluminium trichloride; In ethanol; benzene;

upstream raw materials:

1-benzyl-3-nitrobenzene

3-nitrobenzophenone

2-chloro-5-nitro-benzophenone oxime

hydrogenchloride

Downstream raw materials:

2-[(3-Benzyl-phenylamino)-methylene]-malonic acid diethyl ester

acetic acid-(3-benzyl-anilide)

Refernces

• 1、 -. "Novel SIRT2 protein inhibitor and usage thereof in pharmacy". Paragraph 0085; 0086. . Retrieved 2017/08/28.
• 2、 Mulder, Peter,Mozenson, Olga,Lin, Shuqiong,Ingold. "The unexpected desulfurization of 4-aminothiophenols". . p. 2379 - 2386. Retrieved 2007/10/03.