benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

Base Information

Chemical Name:benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime
CAS No.:1428573-85-6
Molecular Formula:C₁₇H₁₉F₂N₅O₃
Molecular Weight:379.366
Hs Code.:

Synonyms:benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

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Chemical Property of benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

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Technology Process of benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

There total 5 articles about benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 932-90-1,622-31-1,140461-24-1,140461-25-2,622-32-2
syn-benzaldehyde oxime

: 1428573-85-6
benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

Guidance literature:: Multi-step reaction with 4 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 48 h / 20 °C

2: (bis-(2-methoxyethyl)amino)sulfur trufluoride / dichloromethane; tetrahydrofuran / 18 h / 20 °C

3: hydrogenchloride / methanol; 1,4-dioxane / 16 h / 20 °C

4: potassium fluoride / dimethyl sulfoxide / 16 h / 70 °C

With hydrogenchloride; potassium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; (bis-(2-methoxyethyl)amino)sulfur trufluoride; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; dimethyl sulfoxide; acetonitrile; 3: |Staudinger Azide Reduction;
DOI:10.1021/acsmedchemlett.5b00191

Reference yield:

: 42098-25-9
5-chloro-1-methyl-4-nitro-1H-pyrazole

: C₁₃H₁₆F₂N₂O

: 1428573-85-6
benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

Guidance literature:: With potassium fluoride; In dimethyl sulfoxide; at 70 ℃; for 16h;
DOI:10.1021/acsmedchemlett.5b00191

Reference yield:

: 882529-68-2
(Z)-tert-butyl 3-oxo-2,3,6,7-tetrahydro-1H-azepine-1-carboxylate

: 1428573-85-6
benzaldehyde O-6,6-difluoro-1-(1-methyl-4-nitro-1H-pyrazol-5-yl)azepan-4-yloxime

Guidance literature:: Multi-step reaction with 4 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 48 h / 20 °C

2: (bis-(2-methoxyethyl)amino)sulfur trufluoride / dichloromethane; tetrahydrofuran / 18 h / 20 °C

3: hydrogenchloride / methanol; 1,4-dioxane / 16 h / 20 °C

4: potassium fluoride / dimethyl sulfoxide / 16 h / 70 °C

With hydrogenchloride; potassium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; (bis-(2-methoxyethyl)amino)sulfur trufluoride; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; dimethyl sulfoxide; acetonitrile; 3: |Staudinger Azide Reduction;
DOI:10.1021/acsmedchemlett.5b00191