(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

Base Information

Chemical Name:(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane
CAS No.:805235-83-0
Molecular Formula:C₁₅H₁₃ClNO₆P
Molecular Weight:369.698
Hs Code.:

Synonyms:(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

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Chemical Property of (4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

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Technology Process of (4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

There total 10 articles about (4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 777-52-6
1-dichlorophosphoryloxy-4-nitro-benzene

: 632327-18-5
(R)-(+)-1-(3-chlorophenyl)-1,3-propanediol

: 805235-83-0
(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

Guidance literature:: 1-dichlorophosphoryloxy-4-nitro-benzene; (R)-(+)-1-(3-chlorophenyl)-1,3-propanediol; With TEA; In tetrahydrofuran;

With 4-nitro-phenol; TEA; In tetrahydrofuran;
DOI:10.1021/ja031818y

Reference yield:

: 824-78-2
4-nitrophenol sodium salt

: 805235-83-0
(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

Guidance literature:: (S)-(-)-1-(3'-Chlorophenyl)-1,3-Propanediol; With triethylamine; trichlorophosphate; In dichloromethane; at 0 ℃; for 2h;

4-nitrophenol sodium salt; With chlorophosphonic acid; In dichloromethane; for 4h; Heating / reflux;

Reference yield:

: 777-52-6
1-dichlorophosphoryloxy-4-nitro-benzene

: 51699-45-7
(S)-(-)-1-(3'-Chlorophenyl)-1,3-Propanediol

: (+)-(4R)-trans-4-(3-chlorophenyl)-2-(4-nitrophenoxy)-2-oxo-1,3,2-dioxaphosphorinane

: 805235-83-0
(4R)-(+)-trans-2-(4-nitrophenoxy)-2-oxo-4-(3-chlorophenyl)-1,3,2-dioxaphosphorinane

Guidance literature:: 1-dichlorophosphoryloxy-4-nitro-benzene; (S)-(-)-1-(3'-Chlorophenyl)-1,3-Propanediol; With triethylamine; In tetrahydrofuran; at 0 ℃; for 2h;

With 4-nitro-phenol; In triethylamine;