Cycloheptanone, cycloheptylidenehydrazone

Base Information

• Chemical Name: Cycloheptanone, cycloheptylidenehydrazone
• CAS No.: 24214-70-8
• Molecular Formula: C14H24 N2
• Molecular Weight: 220.358
• DSSTox Substance ID: DTXSID00178910
• Nikkaji Number: J31.676H
• Mol file: 24214-70-8.mol

Synonyms:Cycloheptanone, cycloheptylidenehydrazone;24214-70-8;SCHEMBL1255020;DTXSID00178910

Chemical Property of Cycloheptanone, cycloheptylidenehydrazone

Chemical Property:

• Vapor Pressure: 0.000349mmHg at 25°C
• Boiling Point: 329°C at 760 mmHg
• PKA: 9.00±0.20(Predicted)
• Flash Point: 144.9°C
• PSA: 24.72000
• Density: 1.04g/cm³
• LogP: 4.49180
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 220.193948774
• Heavy Atom Count: 16
• Complexity: 218

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCC(=NN=C2CCCCCC2)CC1

Technology Process of Cycloheptanone, cycloheptylidenehydrazone

There total 4 articles about Cycloheptanone, cycloheptylidenehydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cycloheptanol (502-41-0) → N,N'-dicycloheptylidenehydrazine (24214-70-8)

Guidance literature:

With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); potassium tert-butylate; hydrazine hydrate; In toluene; at 125 ℃; for 12h; Schlenk technique; Molecular sieve; Inert atmosphere; Green chemistry;

DOI:10.1039/c9cc01383k

Reference yield: 42.0%

cycloheptanone (502-42-1) → N,N'-dicycloheptylidenehydrazine (24214-70-8)

Guidance literature:

With hydrazine hydrate; In benzene; for 5h; Heating;

DOI:10.3390/11010034

Reference yield:

C42H70O35*C7H12N2 → bicyclo[4.1.0]heptane (286-08-8) + Cycloheptene (628-92-2,45509-99-7) + N,N'-dicycloheptylidenehydrazine (24214-70-8) + methylenecyclohexane (1192-37-6)

Guidance literature:

Product distribution; Irradiation; further cycloheptanespirodiazirine-cyclodextrin complexes;

upstream raw materials:

cycloheptanone

cycloheptanol

Downstream raw materials:

1,1'-azo-bis-cycloheptanecarbonitrile