286-08-8

Basic information

• Product Name: Norcarane
• Synonyms: Norcarane;Bicyclo(4.1.0)heptane;Nsc143399
• CAS NO: 286-08-8
• Molecular Formula: C₇H₁₂
• Molecular Weight: 96.17018
• Mol File: 286-08-8.mol
• Article Data: 12

Chemical Properties

• Melting Point: <25 °C
• Boiling Point: bp 116-117°
• Appearance: /
• Density: 0.914
• Vapor Pressure: 21.6mmHg at 25°C
• Refractive Index: nD25 1.4546
• CAS DataBase Reference: Norcarane(CAS DataBase Reference)
• NIST Chemistry Reference: Norcarane(286-08-8)
• EPA Substance Registry System: Norcarane(286-08-8)

Safety Data

• Hazardous Substances Data: 286-08-8(Hazardous Substances Data)

Usage

General Description

Norcarane is a bicyclic hydrocarbon compound with a molecular formula C8H14. It is a colorless liquid with a sweet, floral odor and is highly flammable. Norcarane is used as a solvent in the manufacturing of rubber and plastics, as well as a chemical intermediate in the synthesis of various organic compounds. It is also used in the production of pharmaceuticals and agrochemicals. Norcarane has low acute toxicity, but prolonged exposure can cause irritation to the eyes, skin, and respiratory system. It is important to handle norcarane with caution and use it in well-ventilated areas.

InChI:InChI=1/C7H12/c1-2-4-7-5-6(7)3-1/h6-7H,1-5H2/t6-,7+

Upstream product

• 34825-90-6 2-Chlorbicyclo<4.1.0>hepten 
• 108296-73-7 C₇H₁₂Pt(Cl)4 
• 95332-99-3 p-tosylhydrazone sodium salt of cycloheptanone 
• 291-64-5 cycloheptane 
• 110-83-8 cyclohexene 
• 74-95-3 1,1-dibromomethane 
• 75-11-6 diiodomethane 
• 50-00-0 formaldehyd 
• 3591-63-7 7-exo-bromo-7-endo-chlorobicyclo<4.1.0>heptane 
• 287-13-8 Tricyclo<4.1.0.0^2,7>heptan 
• 2415-79-4 7,7-dibromonorcarane 
• 86901-19-1 9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium 
• 823-69-8 7,7-dichloro-bicyclo[4.1.0]heptane 
• 109-99-9 tetrahydrofuran 

Downstream Products

• 73326-71-3 2-((1S,2R)-2-Methoxy-cyclohexylmethyl)-3-methyl-succinic acid diethyl ester 
• 81917-06-8 (azidomethyl)cyclohexane 
• 1426126-21-7 C₇H₁₁F 
• 103668-33-3 3-hydroxymethylcyclohexene 
• 88090-52-2 cis-bicyclo<4.1.0>hept-3-ene 
• 40213-64-7 trans-Bicyclo[4.1.0]heptan-3-ol 
• 40213-64-7 cis-Norcaranol-⁽³⁾ 
• 7432-49-7 endo-2-norcaranol 
• 2566-57-6 bicyclo<4.1.0>hept-2-ene 
• 108-88-3 toluene 
• 34825-90-6 2-Chlorbicyclo<4.1.0>hepten 
• 19509-49-0 3-chloromethylcyclohexene 
• 5771-58-4 bicyclo[4.1.0]heptan-2-one 
• 6925-17-3 (3Z)-cyclohept-3-en-1-ol 

Relevant articles and documents

Possible Involvement of Excited Singlet Methylene in the Deoxygenation of Formaldehyde by Atomic Carbon

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The diagnostic substrate bicyclohexane reveals a radical mechanism for bacterial cytochrome P450 in whole cells

(Figure Presented) On home ground: The reaction mechanisms of bacterial alkane-oxidizing cytochrome P450s were determined in their native environment using a novel diagnostic substrate probe, bicyclohexane, in whole cells and cell-free extracts (see picture). Purified P450cam also oxidizes bicyclohexane. Clear evidence for a substrate-based radical with a lifetime of 75-250 ps was obtained.

Use of high pressure in the reduction of organic chlorides with tri-n-butyltin hydride

The use of the high pressure technique enables reduction of organic halides by tri-n-butyltin hydride to be carried out in the absence of a catalyst or free radical initiator.It leads to a better conservation of the structure of the starting material during the reduction.In the case of some unsaturated halides, a new chemoselectivity has been observed in favour of the addition of the hydride on the carbon-carbon double bond.

Platinacyclobutane chemistry: Cis-disubstituted platinacyclobutane complex from bicyclo[4.1.0] heptane

The methodology for the preparation, isolation, and characterization of platinacyclobutanes from cis-disubstituted cyclopropane derivatives is established. In this case the metallacyclobutane was successfully prepared and characterized from bicyclo[4.1.0]