Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

Base Information

Chemical Name:Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane
CAS No.:861445-91-2
Molecular Formula:C11H30 O Si4
Molecular Weight:290.701
Hs Code.:
Mol file:861445-91-2.mol

Synonyms:Tris(trimethylsilyl)silyl vinyl ether;Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

Suppliers and Price of Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIS(TRIMETHYLSILYL)SILYL VINYL ETHER 95.00%
10G
$ 1320.08

American Custom Chemicals Corporation
TRIS(TRIMETHYLSILYL)SILYL VINYL ETHER 95.00%
1G
$ 649.43

Total 5 raw suppliers

Chemical Property of Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

Chemical Property:

Melting Point:51-61 °C
Flash Point:78 °C
PSA：9.23000
LogP:4.34180
Storage Temp.:2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIS(TRIMETHYLSILYL)SILYL VINYL ETHER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xi
Statements: 11-36/37/38
Safety Statements: 26-36/37

MSDS Files:: SDS file from LookChem

Useful:

Uses Super Silyl Protecting GroupsUsed for:Diastereoselective [2+2] cyclizationsCross-Aldol cascade reactionDiastereoselective sequential reactions for generating polyolsAccessing distinct diastereomers and 4-component reactionsSupersilyl-directed aldol reactionsStrong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position

Technology Process of Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

There total 1 articles about Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1873-77-4
tris-(trimethylsilyl)silane

: 75-07-0,9002-91-9
acetaldehyde

: 861445-91-2
tris(trimethylsilyl)-vinyloxy-silane

Guidance literature:: tris-(trimethylsilyl)silane; With trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 1h;

acetaldehyde; With triethylamine; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1021/ja054725k

Reference yield: 89.0%

: 861445-91-2
tris(trimethylsilyl)-vinyloxy-silane

: 2043-61-0
cyclohexanecarbaldehyde

: 3-cyclohexyl-3-tris(trimethylsilyl)siloxypropanal

Guidance literature:: With bis(trifluoromethanesulfonyl)amide; In dichloromethane; at 20 ℃; for 0.25h;
DOI:10.1021/ja054725k

Reference yield: 87.0%

: 861445-91-2
tris(trimethylsilyl)-vinyloxy-silane

: 2043-61-0
cyclohexanecarbaldehyde

: C₄₀H₁₀₂O₄Si₁₂

Guidance literature:: With iodobenzene; bis(trifluoromethanesulfonyl)amide; In dichloromethane; at -40 - 0 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.200907076