(1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane

Base Information

• Chemical Name: (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane
• CAS No.: 599178-35-5
• Molecular Formula: C₂₃H₃₃IO₃
• Molecular Weight: 484.418

Synonyms:(1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane

Chemical Property of (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane

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Technology Process of (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane

There total 1 articles about (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.0^2,7]undecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

methanol (67-56-1) + (1S,2S,3R,7R,9S)-2,5,5,10,10-Pentamethyl-3-((E)-styryl)-4,6-dioxa-tricyclo[7.1.1.02,7]undecane (178435-81-9) → (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.02,7]undecane (599178-35-5)

Guidance literature:

With tetrafluoroboric acid; Barluenga reagent; In diethyl ether; dichloromethane; at -60 - -30 ℃; for 4h;

DOI:10.1021/jo034517f

Reference yield: 96.0%

methanol (67-56-1) + (1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.02,7]undecane (599178-35-5) → (1S,2S,3R,7R,9S)-3-[(1S)-2,2-dimethoxy-1-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.02,7]undecane

Guidance literature:

With boron trifluoride diethyl etherate; [bis(pyridine)iodine]⁺ tetrafluoroborate; In dichloromethane; at 20 ℃;

DOI:10.1002/chem.200500070

Reference yield: 83.0%

(1S,2S,3S,7R,9S)-3-[(1S,2S)-1-iodo-2-methoxy-2-phenylethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.1.02,7]undecane (599178-35-5) → (1S,2S,3R,7R,9S)-3-[(S)-formylphenylmethyl]-2,5,5,10,10-pentamethyl-4,6-dioxatricyclo[7.1.0.02,7]undecane

Guidance literature:

With boron trifluoride diethyl etherate; water; [bis(pyridine)iodine]⁺ tetrafluoroborate; In dichloromethane; at 20 ℃;

DOI:10.1002/chem.200500070

upstream raw materials:

methanol

(1S,2S,3R,7R,9S)-2,5,5,10,10-Pentamethyl-3-((E)-styryl)-4,6-dioxa-tricyclo[7.1.1.0^2,7]undecane

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