(3R^,2S^)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Base Information

Chemical Name:(3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal
CAS No.:116405-73-3
Molecular Formula:C₁₉H₃₂O₄Si
Molecular Weight:352.546
Hs Code.:

(3R<sup>*</sup>,2S<sup>*</sup>)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Synonyms:(3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Suppliers and Price of (3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

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Technology Process of (3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

There total 5 articles about (3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 116376-28-4,116497-22-4
(3R,4R)-6-Benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-hexane-1,2-diol

: 116405-73-3
(3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Guidance literature:: With sodium periodate; In acetone; for 8h; Ambient temperature;
DOI:10.1021/jo00256a023

Reference yield:

: 19790-60-4
3-Benzyloxypropanal

: 116405-73-3
(3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Guidance literature:: Multi-step reaction with 4 steps

2: 75.4 percent / imidazole, benzyl alcohol / dimethylformamide / 48 h / Ambient temperature

3: 85 percent / N-methylmorpholine N-oxide, tert-butyl alcohol, OsO₄ / acetone; H₂O / Ambient temperature

4: 100 percent / aq. NaIO₄ / acetone / 8 h / Ambient temperature

With 1H-imidazole; sodium periodate; osmium(VIII) oxide; 4-methylmorpholine N-oxide; benzyl alcohol; tert-butyl alcohol; In water; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo00256a023

Reference yield:

: 116376-13-7,116376-46-6,116497-21-3
(4R^*,3R^*)-1-(benzyloxy)-4-methoxy-5-hexen-3-ol

: 116405-73-3
(3R^*,2S^*)-5-(benzyloxy)-3-<(tert-butyldimethylsilyl)ocy>-2-methoxypentanal

Guidance literature:: Multi-step reaction with 3 steps

1: 75.4 percent / imidazole, benzyl alcohol / dimethylformamide / 48 h / Ambient temperature

2: 85 percent / N-methylmorpholine N-oxide, tert-butyl alcohol, OsO₄ / acetone; H₂O / Ambient temperature

3: 100 percent / aq. NaIO₄ / acetone / 8 h / Ambient temperature

With 1H-imidazole; sodium periodate; osmium(VIII) oxide; 4-methylmorpholine N-oxide; benzyl alcohol; tert-butyl alcohol; In water; N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo00256a023