methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

Base Information

Chemical Name:methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate
CAS No.:1262991-74-1
Molecular Formula:C₂₁H₂₅N₃O₅
Molecular Weight:399.447
Hs Code.:

Synonyms:methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

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Chemical Property of methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

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Technology Process of methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

There total 6 articles about methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1080-06-4
L-Tyr-OMe

: 92722-14-0
tert-butyl 2-(4-nitrophenyl)diazenecarboxylate

: 1262991-74-1
methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

Guidance literature:: L-Tyr-OMe; With 18-crown-6 ether; potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 1h; Inert atmosphere;

tert-butyl 2-(4-nitrophenyl)diazenecarboxylate; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201004508

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 1262991-74-1
methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

Guidance literature:: Multi-step reaction with 3 steps

1.1: acetonitrile / 20 °C / Inert atmosphere

2.1: manganese(IV) oxide / dichloromethane / 20 °C / Inert atmosphere

3.1: 18-crown-6 ether; potassium carbonate / N,N-dimethyl-formamide / 1.5 h / 20 °C / Inert atmosphere

3.2: Inert atmosphere

With manganese(IV) oxide; 18-crown-6 ether; potassium carbonate; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo202406k

Reference yield:

: 17672-27-4
4-hydrazinobenzonitrile

: 1262991-74-1
methyl (S)-2-amino-3-[4-(4-tert-butyl-azocarboxylatephenoxy)phenyl]propionate

Guidance literature:: Multi-step reaction with 3 steps

1.1: acetonitrile / Inert atmosphere

2.1: manganese(IV) oxide / dichloromethane / Inert atmosphere

3.1: 18-crown-6 ether; potassium carbonate / N,N-dimethyl-formamide / 1.5 h / 20 °C / Inert atmosphere

3.2: Inert atmosphere

With manganese(IV) oxide; 18-crown-6 ether; potassium carbonate; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo202406k