3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

Base Information

Chemical Name:3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane
CAS No.:163396-62-1
Molecular Formula:C₂₃H₄₀O₄Si
Molecular Weight:408.654
Hs Code.:

Synonyms:3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

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Chemical Property of 3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

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Technology Process of 3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

There total 6 articles about 3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 163396-58-5
2-[3-(t-butyldimethylsiloxy)phenyl]-2-isopropoxy-1,1-diisopropylethene

: 163396-62-1
3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

Guidance literature:: With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane; at -78 ℃; for 2h; Irradiation;
DOI:10.1016/S0040-4020(99)00124-6

Reference yield:

: 93351-35-0
isopropyl 3-methoxybenzoate

: 163396-62-1
3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

Guidance literature:: Multi-step reaction with 3 steps

1: 67 percent / titanium(III) trichloride, LiAlH₄, triethylamine / tetrahydrofuran / 0.83 h / Heating

2: 1.) NaSEt, 2.) K₂CO₃ / 1.) DMF, reflux, 3 h, 2.) DMF, room temperature

3: 88 percent / oxygen, tetraphenylporphin / CH₂Cl₂ / 2 h / -78 °C / Irradiation

With lithium aluminium tetrahydride; titanium(III) chloride; oxygen; 5,15,10,20-tetraphenylporphyrin; potassium carbonate; triethylamine; sodium thioethylate; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4020(99)00124-6

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 163396-62-1
3-[3-(t-butyldimethylsiloxy)phenyl]-3-isopropoxy-4,4-diisopropyl-1,2-dioxetane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaSEt, 2.) K₂CO₃ / 1.) DMF, reflux, 3 h, 2.) DMF, room temperature

2: 88 percent / oxygen, tetraphenylporphin / CH₂Cl₂ / 2 h / -78 °C / Irradiation

With oxygen; 5,15,10,20-tetraphenylporphyrin; potassium carbonate; sodium thioethylate; In dichloromethane;
DOI:10.1016/S0040-4020(99)00124-6