[Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl]

Base Information

• Chemical Name: [Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl]
• CAS No.: 405072-70-0
• Molecular Formula: C₃₇H₄₁ClP₂Ru
• Molecular Weight: 684.203
• Mol file: 405072-70-0.mol

Synonyms:[Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl]

Chemical Property of [Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl]

There total 1 articles about [Ru(C₅Me₅)(2,2-bis(diphenylphosphino)propane)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride (92361-49-4) + 2,2’-bis(diphenylphosphino)propane (57585-26-9) → [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)Cl] (405072-70-0)

Guidance literature:

In toluene; byproducts: PPh3; (Ar); using Schlenk techniques; charging of flask with (C5Me5)Ru(PPh3)2Cl, 2,2-bis(diphenylphosphino)propane and toluene, reflux for 3 h, cooling and stirring at ambient temp. overnight; chromy. with diethyl ether as eluents, concn. in vac., crystn. at -35°C overnight, filtration in air, rinsing with ice cold pentane, drying in vac.;

DOI:10.1021/ja0118284

Reference yield:

sodium tetrakis(pentafluorophenyl)-borate (2797-28-6) + [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)Cl] (405072-70-0) + deuterium hydride → [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)(H(2)H)](B(C6F5)4)

Guidance literature:

In dichloromethane-d2; byproducts: NaCl; High Pressure; (Ar); using Schlenk techniques; charging of tube with (C5Me5)Ru(CH3(PPh2)2CCH3)Cl, NaB(ArF)4, and Tiflon stir bar, evacuation, addn. of CD2Cl2 by vac. transfer, filling with 1.1 atm of (2)HH, warming to ambient temp., stirring for 1 h at room temp.; monitoring by NMR;

DOI:10.1021/ja0118284

Reference yield:

sodium tetrakis(pentafluorophenyl)-borate (2797-28-6) + [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)Cl] (405072-70-0) + hydrogen (1333-74-0) → [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)(H)2](B(C6F5)4) + [Ru(C5Me5)(2,2-bis(diphenylphosphino)propane)(H2)](B(C6F5)4)

Guidance literature:

In dichloromethane; (Ar); using Schlenk techniques; treatment of (C5Me5)Ru(CH3C(PPh2)2CH3)Clin CH2Cl2 with H2 (1 atm) in the presence of NaB(ArF)4; monitoring by NMR as mixt. of tautomers;

DOI:10.1021/ja0118284

upstream raw materials:

pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride

2,2’-bis(diphenylphosphino)propane