[(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)]

Base Information

• Chemical Name: [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)]
• CAS No.: 1309857-75-7
• Molecular Formula: C₂₉H₃₃FeN₃
• Molecular Weight: 479.448

Synonyms:[(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)]

Chemical Property of [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)]

Chemical Property:

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Technology Process of [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)]

There total 2 articles about [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η⁴-butadiene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Fe(2,6-(2,6-Me2C6H3NC(Me))2C5H3N)(η4-CH2CHCH(CH2)3)] (1309857-77-9) → [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η4-butadiene)] (1309857-75-7)

Guidance literature:

In benzene-d6; byproducts: CH2CH2; partial dissociation of iron compd. while keeping benzene-d6 soln. at 23°C for 24 h;

DOI:10.1021/ja202992p

Reference yield:

ethene (74-85-1) + [(Fe(2,6-(2,6-Me2C6H3NC(Me))2C5H3N)(dinitrogen))2(μ-dinitrogen)] + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η4-butadiene)] (1309857-75-7)

Guidance literature:

In benzene-d6; addn. of ethylene to C6D6 soln. of iron compd., treatment of obtained (ethylene)iron compd. with butadiene;

DOI:10.1021/ja202992p

Reference yield: 21.0%

[13C2]ethene (51915-19-6) + [(1,1'-(pyridine-2,6-diyl)bis(N-(2,6-dimethylphenyl)ethan-1-imine))Fe(η4-butadiene)] (1309857-75-7) → C29(13)C2H38FeN3 + C4(13)C2H10 + C29(13)C2H38FeN3

Guidance literature:

In benzene-d6; at 20 ℃; for 1h; Glovebox; Inert atmosphere;

DOI:10.1021/jacs.1c08912

upstream raw materials:

ethene

buta-1,3-diene

[Fe(2,6-(2,6-Me2C6H3NC(Me))2C5H3N)(η4-CH2CHCH(CH2)3)]

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