(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

Base Information

Chemical Name:(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester
CAS No.:119909-63-6
Molecular Formula:C₂₁H₃₄O₄
Molecular Weight:350.499
Hs Code.:

Synonyms:(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

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Chemical Property of (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

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Technology Process of (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

There total 7 articles about (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 96149-02-9
(+)-Dimenthyl (1R,2R)-cyclopentane-1,2-dicarboxylate

: 119909-63-6
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / KOH, 30percent aq. H₂O₂ / methanol / 14 h / 50 °C

2: 1.) LDA, 2.) HMPA / 1.) THF, -20 deg C, 1 h, 2.) THF, from -78 to -20 deg C, 5.5 h

With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hydroxide; dihydrogen peroxide; lithium diisopropyl amide; In methanol;
DOI:10.1021/ja00061a003

Reference yield:

: 119909-64-7
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

: 119909-63-6
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

Guidance literature:: With potassium hydroxide; In water; isopropyl alcohol; for 6h; Heating;
DOI:10.1021/ja00188a054

Reference yield:

: 119909-62-5
(1R,2R)-cyclopentane-1,2-dicarboxylic acid mono-(+)-menthyl ester

: 119909-63-6
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) LDA / 1.) THF, -25 deg C, 1 h, 2.) 23 deg C, 16 h

2: 77 percent / diethyl ether / 0.08 h / 23 °C

3: KOH / propan-2-ol; H₂O / 6 h / Heating

With potassium hydroxide; lithium diisopropyl amide; In diethyl ether; water; isopropyl alcohol;
DOI:10.1021/ja00188a054