(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Base Information

Chemical Name:(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester
CAS No.:119909-64-7
Molecular Formula:C₂₂H₃₆O₄
Molecular Weight:364.525
Hs Code.:

Synonyms:(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Suppliers and Price of (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

There total 4 articles about (1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 119909-63-6,119945-34-5
(R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester

: 119909-64-7
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

: 119945-35-6
(1R,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Guidance literature:: In diethyl ether; at 23 ℃; for 0.0833333h;
DOI:10.1021/ja00188a054

Reference yield:

: 119909-62-5
(1R,2R)-cyclopentane-1,2-dicarboxylic acid mono-(+)-menthyl ester

: 119909-64-7
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) LDA / 1.) THF, -25 deg C, 1 h, 2.) 23 deg C, 16 h

2: 77 percent / diethyl ether / 0.08 h / 23 °C

With lithium diisopropyl amide; In diethyl ether;
DOI:10.1021/ja00188a054

Reference yield:

: 96149-02-9
(+)-Dimenthyl (1R,2R)-cyclopentane-1,2-dicarboxylate

: 119909-64-7
(1S,2R)-1-(2-Methyl-allyl)-cyclopentane-1,2-dicarboxylic acid 1-((1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl) ester 2-methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: KOH, 30percent H₂O₂ / methanol / 14 h / 50 °C

2: 1.) LDA / 1.) THF, -25 deg C, 1 h, 2.) 23 deg C, 16 h

3: 77 percent / diethyl ether / 0.08 h / 23 °C

With potassium hydroxide; dihydrogen peroxide; lithium diisopropyl amide; In methanol; diethyl ether;
DOI:10.1021/ja00188a054