Technology Process of 2-(5-bromopentyl)-5-methoxy-3,6-dimethylcyclohexa-2,5-diene-1,4-dione
There total 4 articles about 2-(5-bromopentyl)-5-methoxy-3,6-dimethylcyclohexa-2,5-diene-1,4-dione which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
2-methoxy-3,6-dimethyl-1,4-benzoquinone;
With
ammonium peroxydisulfate;
In
water;
for 1h;
7-bromoheptanoic acid;
With
silver nitrate;
In
water; acetonitrile;
at 75 ℃;
for 4h;
Darkness;
DOI:10.1016/j.bmcl.2014.02.072
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: [bis(acetoxy)iodo]benzene / methanol; water / 16 h / 23 - 40 °C
2.1: ammonium peroxydisulfate / water / 1 h
2.2: 4 h / 75 °C / Darkness
With
ammonium peroxydisulfate; [bis(acetoxy)iodo]benzene;
In
methanol; water;
DOI:10.1016/j.bmcl.2014.02.072
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: dimethyl sulfate; sodium hydroxide / methanol; water / 16 h / 23 °C
2.1: [bis(acetoxy)iodo]benzene / methanol; water / 16 h / 23 - 40 °C
3.1: ammonium peroxydisulfate / water / 1 h
3.2: 4 h / 75 °C / Darkness
With
ammonium peroxydisulfate; [bis(acetoxy)iodo]benzene; dimethyl sulfate; sodium hydroxide;
In
methanol; water;
DOI:10.1016/j.bmcl.2014.02.072
