1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE

Base Information

• Chemical Name: 1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE
• CAS No.: 852634-41-4
• Molecular Formula: C₂₇H₃₅N₂*Cl
• Molecular Weight: 423.041
• Hs Code.: 2933998090
• Mol file: 852634-41-4.mol

Synonyms:1H-Benzimidazolium,1,3-bis(tricyclo[3.3.1.13,7]dec-1-yl)-, chloride (9CI)

Chemical Property of 1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE

Chemical Property:

• PSA: 8.81000
• LogP: 2.78340
• Sensitive.: air sensitive

Purity/Quality:

97% ^*data from raw suppliers

1,3-Bis(1-adamantyl)benzimidazoliumchloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE

There total 3 articles about 1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

N,N’-di(adamantyl)-1,2-diaminobenzene + orthoformic acid triethyl ester (122-51-0) → 1,2-di(1-adamantyl)benzimidazolium chloride (852634-41-4)

Guidance literature:

With hydrogenchloride; at 20 - 80 ℃;

DOI:10.1016/j.tet.2005.07.101

Reference yield:

1-Adamantanamine (768-94-5) → 1,2-di(1-adamantyl)benzimidazolium chloride (852634-41-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent / sodium tert-butoxide; rac-BINAP / Pd₂(dba)3 / toluene / 135 °C

2: 76 percent / HCl / 20 - 80 °C

With hydrogenchloride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; 1: Buchwald-Hartwig amination;

DOI:10.1016/j.tet.2005.07.101

Reference yield:

2,3-dibromobenzene (583-53-9) → 1,2-di(1-adamantyl)benzimidazolium chloride (852634-41-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent / sodium tert-butoxide; rac-BINAP / Pd₂(dba)3 / toluene / 135 °C

2: 76 percent / HCl / 20 - 80 °C

With hydrogenchloride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; 1: Buchwald-Hartwig amination;

DOI:10.1016/j.tet.2005.07.101

upstream raw materials:

orthoformic acid triethyl ester

1-Adamantanamine

2,3-dibromobenzene

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 852634-41-4 1,3-BIS-(ADMANT-1-YL)-BENZIMIDAZOLIUM CHLORIDE

Send

Send

Metric Ton KG G Pound L ML

Send

Send