Bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane

Base Information

• Chemical Name: Bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane
• CAS No.: 849417-33-0
• Molecular Formula: C₂₆H₂₄BrOPPd
• Molecular Weight: 569.774
• DSSTox Substance ID: DTXSID10469083
• Mol file: 849417-33-0.mol

Synonyms:bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane;DTXSID10469083;Bromopalladium(1+) [2-(hydroxymethyl)phenyl]methanide--triphenylphosphane (1/1/1)

Chemical Property of Bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane

Chemical Property:

• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 165-170 °C
• Boiling Point: 360°C at 760 mmHg
• Flash Point: 181.7°C
• PSA: 33.82000
• LogP: 1.68420
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 567.97830
• Heavy Atom Count: 30
• Complexity: 284

Purity/Quality:

98%Min ^*data from raw suppliers

Bromo[(2-(hydroxy-κO)methyl)phenylmethyl-κC](triphenylphosphine)palladium (II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2-]C1=CC=CC=C1CO.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Br[Pd+]

Technology Process of Bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane

There total 1 articles about Bromopalladium(1+);(2-methanidylphenyl)methanol;triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + (2-(bromomethyl)phenyl)methanol (74785-02-7) → bromo[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium (849417-33-0)

Guidance literature:

In toluene; (N2); Schlenk technique; soln. of ligand (1 equiv.) in toluene was addeddropwise to stirred suspn. of Pd complex (1 equiv.) in toluene; mixt. w as stirred at room temp. for 12 h; filtered; washed (Et2O); dried (vac.); crystd. (CH2Cl2/petroleum ether);elem. anal.;

DOI:10.1021/om049131p

Reference yield:

bromo[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium (849417-33-0) → bis[2-(μ-oxomethyl-κO)benzyl-κC(1α)](tris(4-methylphenyl)phosphine)dipalladium monohydrate

Guidance literature:

Multi-step reaction with 2 steps

1: NaH; PPh₃ / tetrahydrofuran

2: toluene

With NaH; PPh₃; In tetrahydrofuran; toluene;

DOI:10.1021/om049131p

Reference yield:

bromo[2-(hydroxymethyl-κO)benzyl-κC(1α)](triphenylphosphine)palladium (849417-33-0) + water (7732-18-5) → bis[2-(μ-oxomethyl-κO)benzyl-κC(1α)](triphenylphosphine)dipalladium monohydrate

Guidance literature:

With NaH; PPh₃; In tetrahydrofuran; byproducts: NaCl, H2; (N2); Schlenk technique; NaH (1 equiv.) in mineral oil was added to suspn. of Pd complex and PPh3 in THF; suspn. was stirred at room temp. for 12 h; filtered; washed (H2O, Et2O); dried (vac.); recrystd. (CH2Cl2/petroleum ether);

DOI:10.1021/om049131p

upstream raw materials:

tetrakis(triphenylphosphine) palladium⁽⁰⁾

(2-(bromomethyl)phenyl)methanol

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