2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

Base Information

• Chemical Name: 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%
• CAS No.: 74785-02-7
• Molecular Formula: C8H9 Br O
• Molecular Weight: 201.063
• Hs Code.: 2906299090
• European Community (EC) Number: 664-279-6
• DSSTox Substance ID: DTXSID50449243
• Nikkaji Number: J1.141.240H
• Wikidata: Q82268654
• Mol file: 74785-02-7.mol

Synonyms:(2-Bromomethylphenyl)methanol;2-(Bromomethyl)benzenemethanol; 2-(Bromomethyl)benzyl alcohol;2-Hydroxymethylbenzylbromide

Chemical Property of 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Melting Point: 66-68 °C
• Refractive Index: 1.599
• Boiling Point: 279.551°C at 760 mmHg
• PKA: 14.18±0.10(Predicted)
• Flash Point: 152.617°C
• PSA: 20.23000
• Density: 1.515g/cm³
• LogP: 2.07380
• Storage Temp.: 2-8°C
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 199.98368
• Heavy Atom Count: 10
• Complexity: 95.3

Purity/Quality:

97% ^*data from raw suppliers

(2-(bromomethyl)phenyl)methanol ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,N
• Statements: 22-34-43-50
• Safety Statements: 26-28-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)CO)CBr

Technology Process of 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%

There total 7 articles about 2-(BROMOMETHYL)BENZYL ALCOHOL, 95% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

phthalyl alcohol (612-14-6) → (2-(bromomethyl)phenyl)methanol (74785-02-7)

Guidance literature:

With hydrogen bromide; In toluene; at 70 ℃; for 4h;

DOI:10.1039/d1cc00081k

Reference yield: 56.0%

phthalyl alcohol (612-14-6) → (2-(bromomethyl)phenyl)methanol (74785-02-7) + α,α'-dibromo-o-xylene (91-13-4)

Guidance literature:

With phosphorus tribromide; In dichloromethane; for 3h; cooling;

DOI:10.1021/ol990168t

Reference yield:

tert-butyl methyl ether (1634-04-4) + carbon tetrabromide (558-13-4) + phthalyl alcohol (612-14-6) → (2-(bromomethyl)phenyl)methanol (74785-02-7)

Guidance literature:

With triphenylphosphine; In dichloromethane;

upstream raw materials:

phthalyl alcohol

tert-butyl methyl ether

carbon tetrabromide

2-(bromomethyl)benzoic acid

Downstream raw materials:

2-<2-(hydroxymethyl)-phenylmethylthio>-1,3-benzoxazole

9-ethyl-1-<(2-hydroxymethyl)benzyl>adenine hydrobromide

isochroman-3-one

[2-(2-phenylethyl)phenyl]methanol