diphenylphosphinate anion

Base Information

• Chemical Name: diphenylphosphinate anion
• CAS No.: 18357-17-0
• Molecular Formula: C₁₂H₁₀O₂P
• Molecular Weight: 217.184
• Mol file: 18357-17-0.mol

Synonyms:diphenylphosphinate anion

Chemical Property of diphenylphosphinate anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of diphenylphosphinate anion

There total 13 articles about diphenylphosphinate anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Natriumdiphenylphosphinoformiat (120175-90-8) → formate (71-47-6) + diphenylphosphinate anion (18357-17-0) + diphenylphosphane (829-85-6)

Guidance literature:

With sodium hydroxide; Product distribution; various pH;

Reference yield:

ethydiphenylphosphine oxide (1733-57-9) → diphenylphosphinate anion (18357-17-0)

Guidance literature:

Multi-step reaction with 4 steps

1: BuLi

2: NaOCl / acetic acid

4: 1.) KOH / 1.) H₂O, THF; 2.) DMSO, 50 deg C

With potassium hydroxide; sodium hypochlorite; n-butyllithium; In acetic acid;

DOI:10.1016/S0040-4039(00)84504-9

Reference yield:

-2-(1-Diphenylphosphinoylethyl)cyclohexanol (144863-57-0,144939-50-4) → diphenylphosphinate anion (18357-17-0)

Guidance literature:

Multi-step reaction with 3 steps

1: NaOCl / acetic acid

3: 1.) KOH / 1.) H₂O, THF; 2.) DMSO, 50 deg C

With potassium hydroxide; sodium hypochlorite; In acetic acid;

DOI:10.1016/S0040-4039(00)84504-9

upstream raw materials:

N-hydroxy-P,P-diphenylphosphinic amide

sodium methylate

C₂₄H₂₁NO₃P₂

-7-(1-Diphenylphosphinoylethyl)-oxepan-2-one

Downstream raw materials:

C₂₄H₂₁NO₃P₂