Formate

Base Information

• Chemical Name: Formate
• CAS No.: 71-47-6
• Molecular Formula: CHO2
• Molecular Weight: 45.0177
• DSSTox Substance ID: DTXSID60221219
• Nikkaji Number: J238.134F
• Wikipedia: Formate
• Wikidata: Q55579895,Q27110012
• Mol file: 71-47-6.mol

Synonyms:aluminum formate;ammonium formate;ammonium tetraformate;calcium formate;chromic formate;cobalt(II) formate dihydrate;cobaltous formate;cupric formate;formate;formic acid;formic acid, 14C-labeled;formic acid, aluminum salt;formic acid, ammonium (2:1) salt;formic acid, ammonium (4:1) salt;formic acid, ammonium salt;formic acid, cadmium salt;formic acid, calcium salt;formic acid, cesium salt;formic acid, cobalt (+2) salt;formic acid, copper (+2) salt;formic acid, copper salt;formic acid, copper, ammonium salt;formic acid, copper, nickel salt;formic acid, cromium (+3) salt;formic acid, cromium (+3), sodium (4:1:1) salt;formic acid, lead (+2) salt;formic acid, lead salt;formic acid, lithium salt;formic acid, magnesium salt;formic acid, nickel (+2) salt;formic acid, nickel salt;formic acid, potassium salt;formic acid, rubidium salt;formic acid, sodium salt;formic acid, sodium salt, 13C-labeled;formic acid, sodium salt, 14C-labeled;formic acid, strontium salt;formic acid, thallium (+1) salt;formic acid, zinc salt;lead formate;lithium formate;magnesium formate;methanoic acid;nickel formate;nickel formate dihydrate;potassium formate;sodium formate;strontium formate;zinc formate

Chemical Property of Formate

Chemical Property:

• Vapor Pressure: 36.5mmHg at 25°C
• Boiling Point: 100.56 °C at 760 mmHg
• Flash Point: 29.888 °C
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 44.997654270
• Heavy Atom Count: 3
• Complexity: 7.5

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-]

Technology Process of Formate

There total 84 articles about Formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

methanolate (3315-60-4) + formic acid ethyl ester (109-94-4) → formate (71-47-6) + C2H5O(1-)*CH4O (8013-52-3)

Guidance literature:

With helium; at 24.85 ℃; under 0.5 Torr; Kinetics; flowing afterglow;

DOI:10.1039/a905632g

Reference yield:

methanol (67-56-1) → formate (71-47-6) + hydrogen (1333-74-0) + carbonate(2-) (3812-32-6)

Guidance literature:

With water; potassium hydroxide; at 60 ℃; Electrolysis;

DOI:10.1016/j.ica.2021.120245

Reference yield:

ethylene glycol (107-21-1) → formate (71-47-6) + hydrogen (1333-74-0) + glycolate (666-14-8)

Guidance literature:

With water; potassium hydroxide; at 60 ℃; Electrolysis;

DOI:10.1016/j.ica.2021.120245

upstream raw materials:

morpholine

1-phenyl-3-(p-methylphenyl)-2,3-epoxy-1-propanone

chalcone epoxide

phenyl-3-(4-chlorophenyl)oxiran-2-ylmethanone

Downstream raw materials:

sodium hydroxide

hydrogen bromide

cadmium(II) formate

carbon dioxide

Refernces

• 1、 Li, Jiawei,Liu, Chunxiao,Xia, Chuan,Xue, Weiqing,Zeng, Jie,Zhang, Menglu,Zheng, Tingting. "Nanoconfinement Engineering over Hollow Multi-Shell Structured Copper towards Efficient Electrocatalytical C?C coupling". supporting information. . Retrieved 2021/12/06.
• 2、 Jeon, Hyo Sang,Timoshenko, Janis,Rettenmaier, Clara,Herzog, Antonia,Yoon, Aram,Chee, See Wee,Oener, Sebastian,Hejral, Uta,Haase, Felix T.,Roldan Cuenya, Beatriz. "Selectivity Control of Cu Nanocrystals in a Gas-Fed Flow Cell through CO2Pulsed Electroreduction". supporting information. p. 7578 - 7587. Retrieved 2021/05/26.