methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Base Information

Chemical Name:methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside
CAS No.:1350556-16-9
Molecular Formula:C₁₅H₁₇NO₅
Molecular Weight:291.304
Hs Code.:

Synonyms:methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Suppliers and Price of methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

There total 11 articles about methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1350556-15-8
methyl 6-formyl-2-benzyloxycarbonylamino-2-deoxy-3-O-methoxycarbonyl-α-D-glucopyranoside

: 1350556-16-9
methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; formic acid; tributylphosphine; triethylamine; In tetrahydrofuran; at -78 - 60 ℃; for 3h; Inert atmosphere; Sonication;
DOI:10.1021/ol2027703

Reference yield:

: 1350556-07-8
methyl 2-benzyloxycarbonylamino-2-deoxy-3-O-methoxycarbonyl-α-D-glucopyranoside

: 1350556-16-9
methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: dmap; triethylamine / dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere

2: triethylamine / dichloromethane / 3 h / 20 °C / Inert atmosphere

3: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere

4: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 3.25 h / 0 - 20 °C / Inert atmosphere

5: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; formic acid; tributylphosphine; triethylamine / tetrahydrofuran / 3 h / -78 - 60 °C / Inert atmosphere; Sonication

With dmap; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; formic acid; tributylphosphine; tetrabutyl ammonium fluoride; sulfur trioxide pyridine complex; acetic acid; triethylamine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol2027703

Reference yield:

: 1350556-11-4
methyl 2-benzyloxycarbonylamino-2-deoxy-3-O-methoxycarbonyl-6-O-tert-butyldimethylsilyl-α-D-glucopyranoside

: 1350556-16-9
methyl 6-formyl-2-benzyloxycarbonylamino-4,5-dehydro-2,3,4-trideoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: triethylamine / dichloromethane / 3 h / 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 16 h / 20 °C / Inert atmosphere

3: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 3.25 h / 0 - 20 °C / Inert atmosphere

4: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; formic acid; tributylphosphine; triethylamine / tetrahydrofuran / 3 h / -78 - 60 °C / Inert atmosphere; Sonication

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; formic acid; tributylphosphine; tetrabutyl ammonium fluoride; sulfur trioxide pyridine complex; acetic acid; triethylamine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol2027703