methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

Base Information

Chemical Name:methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate
CAS No.:282527-08-6
Molecular Formula:C₂₀H₂₀N₂O₇S
Molecular Weight:432.454
Hs Code.:

Synonyms:methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

Chemical Property:

Purity/Quality:

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MSDS Files:: SDS file from LookChem

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Technology Process of methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

There total 3 articles about methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 282527-06-4
methyl 2-[(1-benzyloxyallyl)-(4-nitrobenzenesulfonyl)amino]-(S)-pent-4-enoate

: 282527-08-6
methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

Guidance literature:: Grubbs catalyst first generation; In dichloromethane; at 20 ℃;
DOI:10.1039/b001253j

Reference yield:

: 67515-49-5
1-benzyloxyallene

: 282527-08-6
methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / Et₃N / Pd(OAc)2/dppp / acetonitrile / 16 h / 20 °C

2: 89 percent / RuCl₂[PCy₃]2[=CHPh] / CH₂Cl₂ / 16 h / 20 °C

With triethylamine; palladium diacetate; Grubbs catalyst first generation; 1,3-bis-(diphenylphosphino)propane; In dichloromethane; acetonitrile;
DOI:10.1002/1615-4169(200208)344:6/7<736::AID-ADSC736>3.0.CO;2-8

Reference yield:

: methyl (S)-2-(4-nitrobenzenesulfonylamino)pent-4-enoate

: 282527-08-6
methyl (2S)-6-benzyloxy-1-(4-nitrobenzenesulfonyl)-1,2,3,6-tetrahydropyridine-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / Et₃N / Pd(OAc)2/dppp / acetonitrile / 16 h / 20 °C

2: 89 percent / RuCl₂[PCy₃]2[=CHPh] / CH₂Cl₂ / 16 h / 20 °C

With triethylamine; palladium diacetate; Grubbs catalyst first generation; 1,3-bis-(diphenylphosphino)propane; In dichloromethane; acetonitrile;
DOI:10.1002/1615-4169(200208)344:6/7<736::AID-ADSC736>3.0.CO;2-8