2-iodo-N,N-diphenylaniline

Base Information

• Chemical Name: 2-iodo-N,N-diphenylaniline
• CAS No.: 78600-32-5
• Molecular Formula: C₁₈H₁₄IN
• Molecular Weight: 371.22
• Mol file: 78600-32-5.mol

Synonyms:2-iodo-N,N-diphenylaniline

Chemical Property of 2-iodo-N,N-diphenylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-iodo-N,N-diphenylaniline

There total 8 articles about 2-iodo-N,N-diphenylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

Phenyl triflate (17763-67-6) + diphenylamine (122-39-4) → 2-iodo-N,N-diphenylaniline (78600-32-5)

Guidance literature:

diphenylamine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere; Schlenk technique; Sealed tube;

With bis(2,2,6,6-tetramethyl-1-piperidyl)zinc; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere; Schlenk technique; Sealed tube;

Phenyl triflate; Further stages;

DOI:10.1021/acs.orglett.0c00320

Reference yield: 53.0%

1,2-Diiodobenzene (615-42-9) + diphenylamine (122-39-4) → 2-iodo-N,N-diphenylaniline (78600-32-5)

Guidance literature:

With copper; potassium carbonate; In various solvent(s); for 96h; Heating;

DOI:10.1002/mrc.1270150318

Reference yield: 18.0%

1,2-Diiodobenzene (615-42-9) + N-phenyl-1-naphthylamine (90-30-2) → 2-iodo-N,N-diphenylaniline (78600-32-5)

Guidance literature:

potassium hydroxide; copper; In various solvent(s); at 160 ℃; for 27h;

DOI:10.1021/ja00239a032

upstream raw materials:

1,2-Diiodobenzene

N-phenyl-1-naphthylamine

iodobenzene

diphenylamine

Downstream raw materials:

N-phenylcarbazole