η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium

Base Information

• Chemical Name: η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium
• CAS No.: 251316-71-9
• Molecular Formula: C₁₂H₂₅B₁₀RhSe₂
• Molecular Weight: 538.266
• Mol file: 251316-71-9.mol

Synonyms:η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium

Chemical Property of η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium

There total 2 articles about η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(CH3)5C5Rh][C(COOCH3)CHCHC(COOCH3)SeC2Se(B10H10)] (289660-60-2) + propynoic acid methyl ester (922-67-8) → η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium (251316-71-9) + 1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) + benzene-1,2,4-tricarboxylic acid trimethyl ester (2459-10-1)

Guidance literature:

In toluene; the mixt. in toluene was heated at 70°C for 24 h; solvent was removed, not sepd., detected by NMR spectra;

DOI:10.1021/om0003077

Reference yield:

(C5(CH3)5RhSe2C2B10H10)2(CH3O2CCCH)2 (303982-90-3) + propynoic acid methyl ester (922-67-8) → η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium (251316-71-9) + 1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) + benzene-1,2,4-tricarboxylic acid trimethyl ester (2459-10-1)

Guidance literature:

In toluene; the mixt. in toluene was heated at 70°C for 24 h; solvent was removed, not sepd., detected by NMR spectra;

DOI:10.1021/om0003077

Reference yield:

η5-pentamethylcyclopentadienyl[1,2-dicarba-closo-dodecaborane(12)-diselenolato]rhodium (251316-71-9) + propynoic acid methyl ester (922-67-8) → [(CH3)5C5Rh][C(COOCH3)CHCHC(COOCH3)SeC2Se(B10H10)] (289660-60-2) + (CH3)5C5Rh[SeC(COOCH3)CH2C2Se(B10H9)] (289660-62-4) + 1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) + benzene-1,2,4-tricarboxylic acid trimethyl ester (2459-10-1)

Guidance literature:

In chloroform; the mixt. in CHCl3 was heated at reflux for 24 h; solvent was removed; not sepd., detected by NMR spectra;

DOI:10.1021/om0003077

upstream raw materials:

[(CH₃)5C₅Rh][C(COOCH₃)CHCHC(COOCH₃)SeC₂Se(B₁₀H₁₀)]

propynoic acid methyl ester

(C₅(CH₃)5RhSe₂C₂B₁₀H₁₀)2(CH₃O₂CCCH)2

Downstream raw materials:

[(CH₃)5C₅Rh][C(COOCH₃)CHCHC(COOCH₃)SeC₂Se(B₁₀H₁₀)]

(CH₃)5C₅Rh[SeC(COOCH₃)CH₂C₂Se(B₁₀H₉)]

1,3,5-tris-(methoxycarbonyl)benzene

benzene-1,2,4-tricarboxylic acid trimethyl ester