(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

Base Information

Chemical Name:(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl
CAS No.:483282-48-0
Molecular Formula:C₃₅H₅₃ClCoN₂
Molecular Weight:596.265
Hs Code.:

Synonyms:(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

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Chemical Property of (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

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Technology Process of (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

There total 2 articles about (2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: CoCl₂(thf)_1.5

: 483282-47-9
[Tl(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)]

: 483282-48-0
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

Guidance literature:: In tetrahydrofuran; under N2 atm. using Schlenk techniques; soln. of Tl salt in THF added toa slurry of CoCl2(THF)1.5 in THF; stirred for 2.5 h; filtered; volatiles removed; residue dissolved in Et2O; crystals formed upon standing at room temp. for several hs; elem. anal.;
DOI:10.1021/ja025583m

Reference yield:

: 1318778-51-6,1318778-61-8
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)Co

: 108-90-7
chlorobenzene

: 483282-48-0
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

Guidance literature:: In not given; under Ar or N2; Co complex reacted with C6H5Cl (1 equiv.) at room temp.; detd. by (1)H NMR spectra;
DOI:10.1021/om200991k

Reference yield: 74.2%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 483282-48-0
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

: 420-60-0
trimethyltin fluoride

: 1318778-57-2
[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

Guidance literature:: With KC₈; In tetrahydrofuran; byproducts: KCl, graphite; under Ar or N2; Co complex dissolved in THF; KC8 added; stirred for 1.5 h; allowed to settle; filtered through Celite; Me3SnF added to filtrate;additional THF added; heated at 70°C for 18 h; volatiles removed under reduced pressure; extd. with toluene; filtered through Celite; crystd. from filtrate at -45°C; additional crop ofcrystals obtained by crystn. from mother liquor; elem. anal.;
DOI:10.1021/om200991k