[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

Base Information

Chemical Name:[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2
CAS No.:1318778-57-2
Molecular Formula:C₇₀H₁₀₆Co₂F₂N₄
Molecular Weight:1159.62
Hs Code.:

Synonyms:[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

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Chemical Property of [(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

Chemical Property:

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Technology Process of [(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

There total 11 articles about [(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.2%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 483282-48-0
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl)CoCl

: 420-60-0
trimethyltin fluoride

: 1318778-57-2
[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

Guidance literature:: With KC₈; In tetrahydrofuran; byproducts: KCl, graphite; under Ar or N2; Co complex dissolved in THF; KC8 added; stirred for 1.5 h; allowed to settle; filtered through Celite; Me3SnF added to filtrate;additional THF added; heated at 70°C for 18 h; volatiles removed under reduced pressure; extd. with toluene; filtered through Celite; crystd. from filtrate at -45°C; additional crop ofcrystals obtained by crystn. from mother liquor; elem. anal.;
DOI:10.1021/om200991k

Reference yield: 73.2%

: 1318778-51-6,1318778-61-8
(2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)hept-4-yl)Co

: 420-60-0
trimethyltin fluoride

: 78402-19-4
Sn(Sn(CH₃)3)4

: 1318778-57-2
[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

: 661-69-8
hexamethyldistannane

: 65238-96-2
C₁₀H₃₀Sn₄

: 6031-74-9
Octamethyl-tristannan

Guidance literature:: In tetrahydrofuran; toluene; under Ar or N2; THF and toluene added to Co complex and Me3SnF; mixed; heated at 70°C for 21 h; volatiles removed under reduced pressure; dissolved in toluene-pentane; filtered through Celite; crystd. from filtrate at -45°C; additional crop of crystals obtained by crystn. from mother liquor; elem. anal.;
DOI:10.1021/om200991k

Reference yield:

: 108-90-7
chlorobenzene

: 1318778-57-2
[(2,2,6,6-tetramethyl-3,5-bis(2,4,6-triisopropylphenylimido)hept-4-yl)Co(μ-F)]2

Guidance literature:: Multi-step reaction with 2 steps

1: not given

2: KC₈ / tetrahydrofuran

With KC₈; In tetrahydrofuran;
DOI:10.1021/om200991k