(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Base Information

Chemical Name:(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene
CAS No.:114060-32-1
Molecular Formula:C₂₁H₃₃O₆PS
Molecular Weight:444.529
Hs Code.:

Synonyms:(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Chemical Property:

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Technology Process of (2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

There total 3 articles about (2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 51761-27-4
diethyl phosphorobromidate

: 68690-36-8
(2E)-6-hydroxy-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

: 114060-32-1
(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: With 2,3,5-trimethyl-pyridine;
DOI:10.1021/ja00221a040

Reference yield:

: 53254-60-7
3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene

: 114060-32-1
(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / m-CPBA / CH₂Cl₂ / 0.25 h / 0 °C

2: 86 percent / Al(O-i-Pr)3 / toluene; propan-2-ol / 20 h / 110 °C / Heating

3: 89 percent / collidine

With 2,3,5-trimethyl-pyridine; aluminum isopropoxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; isopropyl alcohol; toluene;
DOI:10.1021/ja00221a040

Reference yield:

: 114060-23-0
(2E)-6,7-epoxy-3,7-dimethyl-1-(p-tolylsulfonyl)-2-octene

: 114060-32-1
(2E)-6-(diethylphosphonooxy)-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / Al(O-i-Pr)3 / toluene; propan-2-ol / 20 h / 110 °C / Heating

2: 89 percent / collidine

With 2,3,5-trimethyl-pyridine; aluminum isopropoxide; In isopropyl alcohol; toluene;
DOI:10.1021/ja00221a040