(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

Base Information

Chemical Name:(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane
CAS No.:1217436-12-8
Molecular Formula:C₁₆H₂₀BF₃O₂
Molecular Weight:312.14
Hs Code.:

Synonyms:(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

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Chemical Property of (Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

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Technology Process of (Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

There total 6 articles about (Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 79756-87-9
1-(prop-1-ynyl)-4-trifluoromethylbenzene

: 73183-34-3
bis(pinacol)diborane

: 1217436-12-8
(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

Guidance literature:: bis(pinacol)diborane; With 1,3-dimethylimidazole-2-thione; copper(l) chloride; sodium t-butanolate; In tetrahydrofuran; at 20 ℃; for 0.166667h; Inert atmosphere;

1-(prop-1-ynyl)-4-trifluoromethylbenzene; With methanol; In tetrahydrofuran; at 20 ℃; for 24h; regioselective reaction; Inert atmosphere; sealed tube;
DOI:10.1039/b919515g

Reference yield: 64.0%

: 79756-87-9
1-(prop-1-ynyl)-4-trifluoromethylbenzene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1217436-12-8
(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

: (E)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

Guidance literature:: With tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate; In dichloromethane; at 0 - 20 ℃; for 1.33333h; regioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201307584

Reference yield:

: 1-(propa-1,2-dien-1-yl)-4-(trifluoromethyl)benzene

: 73183-34-3
bis(pinacol)diborane

: 1217436-12-8
(Z)-4,4,5,5-tetramethyl-2-(1-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

: 4,4,5,5-tetramethyl-2-(3-(4-(trifluoromethyl)phenyl)prop-1-en-2-yl)-1,3,2-dioxaborolane

Guidance literature:: With copper(II) sulfate; triphenylphosphine; benzylamine; In water; at 20 ℃; for 3h; Overall yield = 19 percent; Inert atmosphere;
DOI:10.1039/d0nj02010a