[Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2

Base Information

• Chemical Name: [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2
• CAS No.: 165901-78-0
• Molecular Formula: C₅₄H₅₀I₂N₂O₄P₂Pd₂
• Molecular Weight: 1319.6
• Mol file: 165901-78-0.mol

Synonyms:[Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2

Chemical Property of [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2

There total 2 articles about [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

p-nitrobenzene iodide (636-98-6) + tris(dibenzylideneacetone)dipalladium (0) + tris-(o-tolyl)phosphine (6163-58-2) → [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2 (165901-78-0)

Guidance literature:

In benzene; inert atm.; room temp.; elem. anal.;

DOI:10.1021/ja9806581

Reference yield:

tris-(o-tolyl)phosphine (6163-58-2) → [Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2 (165901-78-0)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: benzene

In benzene;

Reference yield: 86.0%

[Pd[P(o-tolyl)3](p-C6H4NO2)(μ-I)]2 (165901-78-0) + silver fluoride (11113-87-4) → [Pd(C6H4-4-NO2)(P(o-tolyl)3)(μ-F)]2 (929110-39-4,929257-81-8)

Guidance literature:

With P(o-CH₃C₆H₄)3; In toluene; Sonication; (Schlenk, N2) a mixt. of complex, 4 equiv of AgF and 0.1 equiv of phosphine was sonicated in C6H5CH3 at 25°C in the dark for 6 h; ppt. was filtered off, brought to dryness in vac., evacuated for overnight at room temp., triturated with (C2H5)2O for several h at room temp., solid was washed with diethyl ether at room temp. dried in vac. at 70°C for 6 h; elem. anal.;

DOI:10.1021/ja066930l

upstream raw materials:

p-nitrobenzene iodide

tris-(o-tolyl)phosphine

Downstream raw materials:

[(R)-Tol-BINAP]Pd(p-C₆H₄NO₂)I

[Pd(C6H4-4-NO2)(P(o-tolyl)3)(μ-F)]2

[Pd(C6H4-4-NO2)(P(t-Bu)3)(μ-F)]2

(1,3-bis(di-tert-butylphosphino)propane)Pd(C₆H₄-p-NO₂)I