Fe(CO)4(P(C₂H₅)3)

Base Information

• Chemical Name: Fe(CO)4(P(C₂H₅)3)
• CAS No.: 15078-01-0
• Molecular Formula: C₁₀H₁₅FeO₄P
• Molecular Weight: 286.047
• Mol file: 15078-01-0.mol

Synonyms:Fe(CO)4(P(C₂H₅)3)

Chemical Property of Fe(CO)4(P(C₂H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(CO)4(P(C₂H₅)3)

There total 8 articles about Fe(CO)4(P(C₂H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

triiron dodecarbonyl (17685-52-8) + 1-Phenylbut-1-en-3-one (122-57-6) + triethylphosphine (554-70-1) → Fe(CO)4(P(C2H5)3) (15078-01-0) + (benzylideneacetone)dicarbonyl(triethylphosphine)iron(0)

Guidance literature:

In benzene; Irradiation (UV/VIS); N2-atmosphere; stirring of Fe-complex and phosphine (in THF, 70°C, 1 h), filtration, solvent removal (vac.), dissoln. in C6H6, benzylideneacetone addn., irradiation (quartz vessel, 125-W medium-pressure Hg lamp, 16 h); chromy. (SiO2, C6H6, then ethyl acetate/C6H6=1:10), crystn., washing (pentane); elem. anal.;

DOI:10.1016/S0022-328X(00)99303-3

Reference yield:

FePt2(CO)5(P(C2H5)3)3 → iron pentacarbonyl (13463-40-6,37220-42-1) + tricarbonylbis(triethylphosphane)iron (14589-55-0,18533-29-4) + Fe(CO)4(P(C2H5)3) (15078-01-0) + Pt4(CO)5(P(C2H5)3)4

Guidance literature:

With CO; In tetrahydrofuran; CO-atmosphere, stirring (overnight); not isolated, determined by NMR spectroscopy;

Reference yield:

FePt2(CO)5(P(C2H5)3)3 + Fe2Pt(CO)8(P(C2H5)3)2 (120711-64-0) → iron pentacarbonyl (13463-40-6,37220-42-1) + [Pt5(CO)(μ-CO)5(PEt3)4] + Fe(CO)4(P(C2H5)3) (15078-01-0) + Pt4(CO)5(P(C2H5)3)4

Guidance literature:

With CO; In tetrahydrofuran; CO-atmosphere, stirring (overnight); not isolated, determined by NMR spectroscopy;

upstream raw materials:

Fe₂Pt(CO)8(P(C₂H₅)3)2

diiron nonacarbonyl

triiron dodecarbonyl

1-Phenylbut-1-en-3-one