diphenyl biphenyl-4,4'-dicarboxylate

Base Information

• Chemical Name: diphenyl biphenyl-4,4'-dicarboxylate
• CAS No.: 3204-57-7
• Molecular Formula: C₂₆H₁₈O₄
• Molecular Weight: 394.427
• Mol file: 3204-57-7.mol

Synonyms:diphenyl biphenyl-4,4'-dicarboxylate

Chemical Property of diphenyl biphenyl-4,4'-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenyl biphenyl-4,4'-dicarboxylate

There total 3 articles about diphenyl biphenyl-4,4'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

carbon monoxide (201230-82-2) + 4,4'-diiodobiphenyl (3001-15-8) + phenol (108-95-2,27073-41-2) → diphenyl biphenyl-4,4'-dicarboxylate (3204-57-7)

Guidance literature:

With triethylamine; palladium on activated charcoal; In benzene; at 140 ℃; for 6h; under 7500.6 Torr;

DOI:10.1055/s-2003-37646

Reference yield: 28.0%

carbon monoxide (201230-82-2) + 4-(4-bromophenyl)bromobenzene (92-86-4) + phenol (108-95-2,27073-41-2) → diphenyl biphenyl-4,4'-dicarboxylate (3204-57-7) + phenyl 4'-bromobiphenyl-4-carboxylate

Guidance literature:

With 1,3-bis-(diphenylphosphino)propane; triethylamine; palladium dichloride; In benzene; at 120 ℃; for 3h; under 7500.6 Torr;

DOI:10.1246/bcsj.67.563

Reference yield:

→ diphenyl biphenyl-4,4'-dicarboxylate (3204-57-7)

Guidance literature:

Entspr. Dimethylester, Phenol;

upstream raw materials:

carbon monoxide

4-(4-bromophenyl)bromobenzene

phenol

4,4'-diiodobiphenyl