methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside
CAS No.:68880-90-0
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

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Technology Process of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

There total 1 articles about methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 68907-48-2
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-3-O<(thiomethyl)-thiocarbonyl>-α-D-altro-pyranoside

: 68880-90-0
methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

Guidance literature:: With tri-n-butyl-tin hydride; In toluene; Heating;
DOI:10.1139/v82-050

Reference yield:

: 68880-90-0
methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

: 68880-95-5
methyl 2,3,4-trideoxy-2,4-di-C-methyl-6-O-(triphenylmethyl)-α-D-lyxo-hexopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / p-toluenesulfonic acid monohydrate / methanol / 2.5 h / Ambient temperature

2: 86 percent / pyridine / 72 h / Ambient temperature

3: 81 percent / CrO₃ / pyridine; CH₂Cl₂ / 18 h / Ambient temperature

4: 82 percent / n-butyllithium / diethyl ether / 28 h / Heating

5: 80 percent / H₂ / tris(triphenylphophine)rhodium chloride / benzene / 24 h / 760 Torr

With chromium(VI) oxide; n-butyllithium; hydrogen; toluene-4-sulfonic acid; Wilkinson's catalyst; In pyridine; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1139/v82-050

Reference yield:

: 68880-90-0
methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside

: 79646-64-3
methyl 2,3,4-trideoxy-2,4-di-C-methyl-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / p-toluenesulfonic acid monohydrate / methanol / 2.5 h / Ambient temperature

2: 86 percent / pyridine / 72 h / Ambient temperature

3: 81 percent / CrO₃ / pyridine; CH₂Cl₂ / 18 h / Ambient temperature

4: 82 percent / n-butyllithium / diethyl ether / 28 h / Heating

5: 9 percent / H₂ / tris(triphenylphophine)rhodium chloride / benzene / 24 h / 760 Torr

With chromium(VI) oxide; n-butyllithium; hydrogen; toluene-4-sulfonic acid; Wilkinson's catalyst; In pyridine; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1139/v82-050