68880-95-5

Upstream product

• 73656-98-1 methyl 2,3,4-trideoxy-4-C-methyl-2-C-methylene-6-O-(triphenylmethyl)-α-D-threo-hexopyranoside 
• 68880-94-4 methyl 2,3,4-trideoxy-2-C-methyl-6-O-triphenylmethyl-α-D-threo-hexopyranoside 
• 68880-93-3 methyl 2,3-dideoxy-2-C-methyl-6-O-triphenylmethyl-α-D-threo-hexopyranosid-4-ulose 
• 68880-90-0 methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside 
• 35303-94-7 (2S,6S)-2-Methoxy-6-trityloxymethyl-6H-pyran-3-one 
• 66149-56-2 methyl 3,4-dideoxy-4-C-methyl-6-O-(triphenylmethyl)-α-D-threo-hexopyranosid-2-ulose 
• 68907-48-2 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-3-O<(thiomethyl)-thiocarbonyl>-α-D-altro-pyranoside 
• 68880-92-2 methyl 2,3-dideoxy-2-C-methyl-6-O-(triphenylmethyl)-α-D-arabino-hexopyranoside 
• 68880-91-1 methyl 2,3-dideoxy-2-C-methyl-α-D-arabino-hexopyranoside 
• 76-83-5 trityl chloride 
• 492-62-6 alpha-D-glucopyranose 

Downstream Products

• 73684-08-9 methyl 2,3,4-trideoxy-2,4-C-dimethyl-6-O-(p-toluenesulfonyl)-α-D-lyxo-hexopyranoside 
• 110561-04-1 13-O-benzoyl-1,3-O-cyclohexylidene-2,4,5,6,8,9,10,12-octadeoxy-11-O-(1-ethoxyethyl)-4,8,10,12-C-tetramethyl-D-gluco(and D-manno)-D-threo-7-trideculose trimethylene dithioacetal 
• 82335-98-6 serricornin acetate <(4S,6R,7R)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 80516-28-5 (2S,3R,5R)-1-Benzyloxy-3,5-dimethyl-oct-7-ene-2,6-diol 
• 73657-04-2 8-(benzyloxy)-4,6-dimethyl-3-oxo-1-octen-7-ol 
• 80516-19-4 methyl 6-O-benzyl-2,3,4-trideoxy-2,4-di-C-methyl-α-D-lyxo-hexopyranoside 
• 80516-26-3 6-O-benzyl-2,3,4-trideoxy-2,4-di-C-methyl-D-lyxo-hexopyranose 
• 59014-03-8 (-)-α-multistriatin 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF ANTIBIOTIC A23187 (CALCIMYCIN) FROM D-GLUCOSE

The fully stereocontrolled synthesis A23187 by using the chirons derived from D-glucose is described.

STEREOSELECTIVE SYNTHESIS OF(-)-α-MULTISTRIATIN FROM D-GLUCOSE

D-glucose was converted into (-)-α-multistriatin, the aggregation pheromone of the Europian elm bark beetle, via a highly stereoselective eighteen-step route

Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 4. Synthesis of (-)-α-Multistriatin

The precursor for (-)-α-multistriatin (alkyl 2,3,4-trideoxy-2,4-di-C-methyl-α-D-lyxo-hexopyranoside) may be approached from the corresponding isomeric 4-oxo-2-C-methyl- or 2-oxo-4-C-methylpyranosides by (a) methylenation followed by (b) hydrogenation.The