4-toluene-d7-sulfinyl chloride

Base Information

• Chemical Name: 4-toluene-d7-sulfinyl chloride
• CAS No.: 87433-31-6
• Molecular Formula: C₇H₇ClOS
• Molecular Weight: 181.595
• Mol file: 87433-31-6.mol

Synonyms:4-toluene-d7-sulfinyl chloride

Chemical Property of 4-toluene-d7-sulfinyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-toluene-d7-sulfinyl chloride

There total 2 articles about 4-toluene-d7-sulfinyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

C7(2)H7O2S(1-)*Na(1+) → 4-toluene-d7-sulfinyl chloride (87433-31-6)

Guidance literature:

With thionyl chloride;

DOI:10.1021/jo00173a005

Reference yield:

(2)H8-toluene (2037-26-5) → 4-toluene-d7-sulfinyl chloride (87433-31-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium sulfite

2: 46 percent / SOCl₂

With thionyl chloride; sodium sulfite;

DOI:10.1021/jo00173a005

Reference yield: 91.0%

3-methoxy-N-methyl-N,2,4,6-tetradeuteroaniline (87433-28-1) + 4-toluene-d7-sulfinyl chloride (87433-31-6) → N-(3-methoxy-2,4,6-trideuteriophenyl)-N-methylheptadeuterio-4-toluenesulfinamide (87433-16-7)

Guidance literature:

With pyridine; In diethyl ether; Title compound not separated from byproducts; 1.) -78 deg C, 1 min, 2.) RT;

DOI:10.1021/jo00173a005

upstream raw materials:

⁽²⁾H₈-toluene

Downstream raw materials:

N-(3-methoxy-2,4,6-trideuteriophenyl)-N-methylheptadeuterio-4-toluenesulfinamide