[N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)]

Base Information

• Chemical Name: [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)]
• CAS No.: 81952-53-6
• Molecular Formula: C₁₂H₄Fe₃NO₁₀*C₃₆H₃₀NP₂
• Molecular Weight: 1028.29
• Mol file: 81952-53-6.mol

Synonyms:[N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)]

Chemical Property of [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)]

There total 1 articles about [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Fe₃H(CO)10(CNCH₃)]^(1-)=[N(P(C₆H₅)3)2][Fe₃H(CO)10(CNCH₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{PPN}{Fe3(μ2-H)(CO)11} + methyl isocyanate (593-75-9,685498-28-6) → [N(P(C6H5)3)2](1+)*[Fe3H(CO)10(CNCH3)](1-)=[N(P(C6H5)3)2][Fe3H(CO)10(CNCH3)] (81952-53-6)

Guidance literature:

In dichloromethane; under N2, educts stirred in CH2Cl2 at room temp.; evapd.;

DOI:10.1039/DT9820000043

Reference yield:

[N(P(C6H5)3)2](1+)*[Fe3H(CO)10(CNCH3)](1-)=[N(P(C6H5)3)2][Fe3H(CO)10(CNCH3)] (81952-53-6) + trifluorormethanesulfonic acid (1493-13-6) → triiron dodecarbonyl (17685-52-8) + [HFe3(CO)10(μ2-CNHMe)]

Guidance literature:

In diethyl ether; under N2, crude Fe complex dissolved in Et2O, soln. of CF3SO3H in Et2O added, stirred at room temp. for 10 min; evapd., chromd. (SiO2, light petroleum-benzene), purified by preparative t.l.c.; elem. anal.;

DOI:10.1039/DT9820000043

upstream raw materials:

methyl isocyanate

Downstream raw materials:

triiron dodecarbonyl