methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

Base Information

Chemical Name:methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside
CAS No.:78841-77-7
Molecular Formula:C₁₅H₂₂O₆S
Molecular Weight:330.402
Hs Code.:

Synonyms:methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

Suppliers and Price of methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

There total 30 articles about methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.5%

: 124-63-0
methanesulfonyl chloride

: 78841-76-6
methyl 5-O-benzyl-2,6-dideoxy-α-L-lyxo-hexofuranoside

: 78841-77-7
methyl 5-O-benzyl-2,6-dideoxy-3-O-(methylsulfonyl)-α-L-lyxo-hexofuranoside

Guidance literature:: In pyridine; for 4h; Ambient temperature;
DOI:10.1016/S0008-6215(00)80395-X

Reference yield:

: 7057-10-5
1,2-O-isopropylidene-α-D-5-deoxyglucurono-6,3-lactone

: 78841-77-7,111651-75-3
Methanesulfonic acid (2R,3R)-2-((S)-1-benzyloxy-ethyl)-5-methoxy-tetrahydro-furan-3-yl ester

Guidance literature:: Multi-step reaction with 7 steps

1: Amberlite IR 120 (H) resin / Heating

2: 54 percent / silver oxide / benzene

3: conc. HCl

4: 60 percent / DIBAL / CH₂Cl₂ / -78 °C

5: IR 120 resin / Heating

6: 65 percent / hydrogen / Raney nickel / 48 h

7: pyridine

With pyridine; hydrogenchloride; Amberlite IR 120 (H) resin; IR 120 resin; hydrogen; diisobutylaluminium hydride; silver(l) oxide; nickel; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(00)95361-9

Reference yield:

: 57569-46-7
(3aR,3bR,6aS,7aR)-6-Chloro-2,2-dimethyl-tetrahydro-furo[2',3':4,5]furo[2,3-d][1,3]dioxol-5-one

: 78841-77-7,111651-75-3
Methanesulfonic acid (2R,3R)-2-((S)-1-benzyloxy-ethyl)-5-methoxy-tetrahydro-furan-3-yl ester

Guidance literature:: Multi-step reaction with 8 steps

1: tri-n-butyltin hydride / AIBN / toluene / Heating

2: Amberlite IR 120 (H) resin / Heating

3: 54 percent / silver oxide / benzene

4: conc. HCl

5: 60 percent / DIBAL / CH₂Cl₂ / -78 °C

6: IR 120 resin / Heating

7: 65 percent / hydrogen / Raney nickel / 48 h

8: pyridine

With pyridine; hydrogenchloride; Amberlite IR 120 (H) resin; IR 120 resin; hydrogen; tri-n-butyl-tin hydride; diisobutylaluminium hydride; silver(l) oxide; 2,2'-azobis(isobutyronitrile); nickel; In dichloromethane; toluene; benzene;
DOI:10.1016/S0040-4039(00)95361-9