benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

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Chemical Name:benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester
CAS No.:864653-60-1
Molecular Formula:C₂₉H₄₁NO₅Si₂
Molecular Weight:539.819
Hs Code.:

Synonyms:benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

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Chemical Property of benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

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Technology Process of benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

There total 8 articles about benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 864653-61-2
benzoic acid 3-[(6-iodo-benzo[1,3]dioxol-5-ylmethyl)-trimethylsilanylmethyl-amino]-3-trimethylsilanyl-propyl ester

: 78-94-4,25038-87-3
methyl vinyl ketone

: 864653-60-1
benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

Guidance literature:: With potassium carbonate; palladium diacetate; triphenylphosphine; In acetonitrile; for 12h; Heating;
DOI:10.1021/ol051321o

Reference yield: 60.0%

: 864653-61-2
benzoic acid 3-[(6-iodo-benzo[1,3]dioxol-5-ylmethyl)-trimethylsilanylmethyl-amino]-3-trimethylsilanyl-propyl ester

: 140-88-5,9003-32-1
ethyl acrylate

: 864653-60-1
benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

Guidance literature:: With palladium diacetate; potassium carbonate; triphenylphosphine; In acetonitrile; for 12h; Reflux;
DOI:10.1002/ejoc.201100601

Reference yield:

: 146514-22-9
2-Methyl-4-trimethylsilanyl-[1,3]oxazinane-3-carboxylic acid tert-butyl ester

: 864653-60-1
benzoic acid 3-{[6-(3-oxo-but-1-enyl)-benzo[1,3]dioxol-5-ylmethyl]-trimethylsilanylmethyl-amino}-3-trimethylsilanyl-propyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / HCl / dioxane / 1 h / Heating

2: 80 percent / K₂CO₃ / acetonitrile / 10 h / Heating

3: K₂CO₃ / acetonitrile / 8 h / Heating

4: 6 g / triethylamine / CH₂Cl₂ / 6 h / 20 °C

5: 60 percent / K₂CO₃ / Pd(OAc)2; PPh₃ / acetonitrile / 12 h / Heating

With hydrogenchloride; potassium carbonate; triethylamine; palladium diacetate; triphenylphosphine; In 1,4-dioxane; dichloromethane; acetonitrile; 5: Heck reaction;
DOI:10.1021/ol051321o